Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Bromination is one of the most important transformations in organic synthesis and can be
carried out using bromine and many other bromo compounds. Use of molecular bromine in …

C–H bonds are ubiquitous structural units of organic molecules. Although these bonds are
generally considered to be chemically inert, the recent emergence of methods for C–H …

The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

Recent developments in catalytic C–H amination are discussed in this feature article. The
careful design of reagents and catalysts now provides efficient conditions for exquisitely …

Transition metal-catalyzed N-atom transfer reactions of azides provide efficient ways to
construct new carbon–nitrogen and sulfur–nitrogen bonds. These reactions are inherently …

It has been a long time since C–H bond oxidations first attracted chemists' attention. In the
last several decades, C–H bond oxidation has been extensively investigated and applied in …

Direct C–H amination of arenes offers a straightforward route to aniline compounds without
necessitating aryl (pseudo) halides as the starting materials. The recent development in this …

Direct C–H bond functionalization to form C–N bonds via nitrenoid insertion is one of the
most effective strategies to construct N-functionalized molecules of importance. In this …