Spin hyperpolarization in modern magnetic resonance

J Eills, D Budker, S Cavagnero, EY Chekmenev… - Chemical …, 2023 - ACS Publications
Magnetic resonance techniques are successfully utilized in a broad range of scientific
disciplines and in various practical applications, with medical magnetic resonance imaging …

Current applications of 19F NMR to studies of protein structure and dynamics

JL Kitevski-LeBlanc, RS Prosser - Progress in nuclear magnetic resonance …, 2012 - Elsevier
While traditional 1H, 13C, and 15N (HCN) solution state NMR protocols provide a wealth of
data on protein structure and dynamics, 19F NMR provides a unique perspective of …

Enlightening the photoactive site of channelrhodopsin-2 by DNP-enhanced solid-state NMR spectroscopy

J Becker-Baldus, C Bamann… - Proceedings of the …, 2015 - National Acad Sciences
Channelrhodopsin-2 from Chlamydomonas reinhardtii is a light-gated ion channel. Over
recent years, this ion channel has attracted considerable interest because of its unparalleled …

Photo-CIDNP spectroscopy

M Goez - Annual reports on NMR Spectroscopy, 2009 - Elsevier
Photo-CIDNP spectroscopy relies on a unique interplay of magnetic interactions, diffusion,
and chemical reactivity; it possesses all the advantages of NMR spectroscopy but responds …

Dynamic Nuclear Polarization of 17O: Direct Polarization

VK Michaelis, B Corzilius, AA Smith… - The Journal of Physical …, 2013 - ACS Publications
Dynamic nuclear polarization of 17O was studied using four different polarizing agents: the
biradical TOTAPOL and the monoradicals trityl and SA-BDPA, as well as a mixture of the …

The electronic structure of the primary electron donor of reaction centers of purple bacteria at atomic resolution as observed by photo-CIDNP 13C NMR

E Daviso, S Prakash, A Alia, P Gast… - Proceedings of the …, 2009 - National Acad Sciences
Composed of the two bacteriochlorophyll cofactors, PL and PM, the special pair functions as
the primary electron donor in bacterial reaction centers of purple bacteria of Rhodobacter …

Fast-pulsing LED-enhanced NMR: A convenient and inexpensive approach to increase NMR sensitivity

H Yang, H Hofstetter, S Cavagnero - The Journal of chemical physics, 2019 - pubs.aip.org
Low-concentration photochemically induced dynamic nuclear polarization (LC-photo-
CIDNP) has recently emerged as a powerful technology for the detection of aromatic amino …

Dynamic nuclear polarization enhanced NMR in the solid-state

U Akbey, WT Franks, A Linden… - … Methods in NMR …, 2013 - Springer
Nuclear magnetic resonance (NMR) spectroscopy is one of the most commonly used
spectroscopic techniques to obtain information on the structure and dynamics of biological …

The solid-state photo-CIDNP effect

J Matysik, A Diller, E Roy, A Alia - Photosynthesis research, 2009 - Springer
The solid-state photo-CIDNP effect is the occurrence of a non-Boltzmann nuclear spin
polarization in rigid samples upon illumination. For solid-state NMR, which can detect this …

Electron− nuclear spin dynamics in a bacterial photosynthetic reaction center

E Daviso, A Alia, S Prakash, A Diller… - The Journal of …, 2009 - ACS Publications
The solid-state photo-CIDNP effect is known to occur in natural photosynthetic reaction
centers (RCs) where it can be observed by magic-angle spinning (MAS) NMR as strong …