Tracing the primordial chemical life of glycine: a review from quantum chemical simulations

A Rimola, N Balucani, C Ceccarelli… - International journal of …, 2022 - mdpi.com
Glycine (Gly), NH2CH2COOH, is the simplest amino acid. Although it has not been directly
detected in the interstellar gas-phase medium, it has been identified in comets and …

Miller experiments in atomistic computer simulations

AM Saitta, F Saija - Proceedings of the National Academy of …, 2014 - National Acad Sciences
The celebrated Miller experiments reported on the spontaneous formation of amino acids
from a mixture of simple molecules reacting under an electric discharge, giving birth to the …

Formamide reaction network in gas phase and solution via a unified theoretical approach: Toward a reconciliation of different prebiotic scenarios

F Pietrucci, AM Saitta - … of the National Academy of Sciences, 2015 - National Acad Sciences
Increasing experimental and theoretical evidence points to formamide as a possible hub in
the complex network of prebiotic chemical reactions leading from simple precursors like H2 …

A chemical link between methylamine and methylene imine and implications for interstellar glycine formation

PR Joshi, YP Lee - Communications chemistry, 2022 - nature.com
Methylamine CH3NH2 is considered to be an important precursor of interstellar amino acid
because hydrogen abstraction might lead to the aminomethyl radical• CH2NH2 that can …

Pathways to meteoritic glycine and methylamine

JC Aponte, JE Elsila, DP Glavin, SN Milam… - ACS Earth and Space …, 2017 - ACS Publications
Glycine and methylamine are meteoritic water-soluble organic compounds that provide
insights into the processes that occurred before, during, and after the formation of the Solar …

Gas-Phase vs. Grain-Surface Formation of Interstellar Complex Organic Molecules: A Comprehensive Quantum-Chemical Study

B Martínez-Bachs, A Rimola - International journal of molecular sciences, 2023 - mdpi.com
Several organic chemical compounds (the so-called interstellar complex organic molecules,
iCOMs) have been identified in the interstellar medium (ISM). Examples of iCOMs are …

Chemical reactions induced in frozen formic acid by heavy ion cosmic rays

DPP Andrade, ALF de Barros, S Pilling… - Monthly Notices of …, 2013 - academic.oup.com
We studied the effects produced by the interaction of heavy ion cosmic rays with interstellar
and cometary organic molecules in the solid phase. Formic acid (HCOOH) ice at 15 K was …

The influence of crystallinity degree on the glycine decomposition induced by 1 MeV proton bombardment in space analog conditions

S Pilling, LAV Mendes, V Bordalo, CFM Guaman… - Astrobiology, 2013 - liebertpub.com
Glycine is the simplest proteinaceous amino acid and is present in all life-forms on Earth. In
aqueous solutions, it appears mainly as zwitterion glycine (+ NH3CH2COO−); however, in …

The effect of broadband soft X-rays in SO2-containing ices: implications on the photochemistry of ices toward young stellar objects

S Pilling, A Bergantini - The Astrophysical Journal, 2015 - iopscience.iop.org
We investigate the effects produced mainly by broadband soft X-rays up to 2 keV (plus fast
(∼ keV) photoelectrons and low-energy (∼ eV) induced secondary electrons) in the ice …

Enantiodetermining processes in the synthesis of alanine, serine, and isovaline

Q Liao, P Xie, Z Wang - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
In this study, quantum chemical calculations were used to explore the synthesis of three
chiral α-amino acids, specifically alanine, serine, and isovaline, from reactants found in …