This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Conspectus Biologically active compounds and pharmaceutically relevant intermediates
often feature sterically congested stereogenic centers, in particular, carbon stereocenters …

A copper-catalyzed diastereo-and enantioselective decarboxylative [3+ 2] cyclization
reaction of alkyne-substituted cyclic carbamates with azlactones has been established. A …

Palladium on charcoal (Pd/C) has lots of salient merits:(i) it is a cheap and commercial
source of palladium,(ii) it shows efficient catalytic activity even without ligands,(iii) as a …

This review highlights the developments in palladium-catalyzed allylic C–H functionalization
from early 2014 to the present date. π-Allylpalladium chemistry emphasizes the research …

A PdII‐catalyzed asymmetric aminohydroxylation of 1, 3‐dienes with N‐tosyl‐2‐
aminophenols was developed by making use of a chiral pyridinebis (oxazoline) ligand. The …

The wide abundance of γ-lactones in natural products and bioactive targets calls for suitable
building blocks for their enantioselective synthesis. β, γ-Unsaturated γ-butenolides …

The first enantioselective synthesis of α‐allenylic amides and ketones through allenylic
alkylation of vinyl azides is reported. In these chemodivergent reactions, cooperatively …

A straightforward approach for the asymmetric synthesis of multifunctionalized γ-lactams,
including those bearing two tetrasubstituted stereogenic centers, has been developed …

A palladium-catalyzed oxidative tandem process of enallenols was accomplished within a
homogeneous/heterogeneous catalysis manifold, setting the stage for the highly …