Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations

SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …

ROMP and MCP as versatile and forceful tools to fabricate dendronized polymers for functional applications

X Liu, F Liu, W Liu, H Gu - Polymer Reviews, 2021 - Taylor & Francis
Due to their unique physical and chemical features, dendronized polymers (DPs) have
received increasing attention in various fields such as hierarchically structured materials …

Bottlebrush polymers via ring-opening metathesis polymerization (ROMP): Synthesis, properties and applications

SR Rout, G Kenguva, S Mansuri, KR Manu… - European Polymer …, 2024 - Elsevier
Bottlebrush polymers (BBPs) are a class of branch or graft macromolecules with polymeric
side chains attached to linear backbone leading to cylindrical or worm like structures. Due to …

Solvent effects in grafting-through ring-opening metathesis polymerization

SE Blosch, M Alaboalirat, CB Eades… - …, 2022 - ACS Publications
Ring-opening metathesis polymerization (ROMP) utilizing Grubbs' third-generation catalyst
((H2IMes)(Cl) 2 (pyr) 2RuCHPh) shows the characteristics of living polymerizations …

Mechanochemical reactivity of bottlebrush and dendronized polymers: solid vs. solution states

J Noh, GI Peterson, TL Choi - … Chemie International Edition, 2021 - Wiley Online Library
We explored the mechanochemical degradation of bottlebrush and dendronized polymers in
solution (with ultrasonication, US) and solid states (with ball‐mill grinding, BMG). Over 50 …

Efficient synthesis of asymmetric miktoarm star polymers

AE Levi, L Fu, J Lequieu, JD Horne… - …, 2020 - ACS Publications
Asymmetric miktoarm star polymers produce unique material properties, yet existing
synthetic strategies are beleaguered by complicated reaction schemes restricted in both the …

Ring-opening metathesis polymerization of norbornene–benzoladderene (macro) monomers

SJ Scannelli, M Alaboalirat, D Troya, JB Matson - Polymer Chemistry, 2023 - pubs.rsc.org
Norbornene-based monomers are common starting points in ring-opening metathesis
polymerization (ROMP) due to their high ring strain, and recent reports highlight how the …

Efficient Metal-Free Norbornadiene–Maleimide Click Reaction for the Formation of Molecular Bottlebrushes

Z Li, W Hou, Y Li, J Xu, Y Shi, Y Chen - Macromolecules, 2021 - ACS Publications
A highly efficient metal-free grafting-onto strategy based on the cyclopentadiene (Cp)–
maleimide click reaction was developed for the preparation of molecular bottlebrushes …

Triblock Glycopolymers with Two 10-mer Blocks of Activating Sugars Enhance the Activation of Acrosomal Exocytosis in Mouse Sperm

LC Mendez, M Kennedy, SR Bhatia… - ACS Bio & Med Chem …, 2024 - ACS Publications
Carbohydrate recognition is imperative for the induction of sperm acrosomal exocytosis
(AE), an essential phenomenon in mammalian fertilization. In mouse sperm, polynorbornene …

How does stiffness of polymer chains affect their adsorption transition?

A Milchev, K Binder - The Journal of chemical physics, 2020 - pubs.aip.org
The adsorption transition and the structure of semiflexible adsorbed macromolecules are
studied by a molecular dynamics simulation of a coarse-grained, bead-spring type model …