Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications

K Kirakci, MA Shestopalov, K Lang - Coordination Chemistry Reviews, 2023 - Elsevier
The luminescent octahedral molybdenum, tungsten, and rhenium cluster complexes have
attracted a broad interest in the past decades for the design of photofunctional materials …

Functional materials containing luminescent octahedral halide clusters of molybdenum and tungsten: Diversity of synthetic approaches and binding modes

NA Vorotnikova, YA Vorotnikov… - Coordination Chemistry …, 2024 - Elsevier
The history of the chemistry of halide octahedral cluster complexes began long ago in the
19th century, but to this day these compounds have not lost their topicality or even become …

Synthetic Tuning of Redox, Spectroscopic, and Photophysical Properties of {Mo6I8}4+ Core Cluster Complexes by Terminal Carboxylate Ligands

MA Mikhailov, KA Brylev, PA Abramov… - Inorganic …, 2016 - ACS Publications
The reactions between the tetra-n-butylammonium salt of [{Mo6I8} I6] 2–and silver
carboxylates RCOOAg (R= CH3 (1), C (CH3) 3 (2), α-C4H3O (3), C6H5 (4), α-C10H7 (5), or …

X-ray inducible luminescence and singlet oxygen sensitization by an octahedral molybdenum cluster compound: a new class of nanoscintillators

K Kirakci, P Kubát, K Fejfarová, J Martincik… - Inorganic …, 2016 - ACS Publications
Newly synthesized octahedral molybdenum cluster compound (n-Bu4N) 2 [Mo6I8 (OOC-1-
adamantane) 6] revealed uncharted features applicable for the development of X-ray …

Cellular internalisation, bioimaging and dark and photodynamic cytotoxicity of silica nanoparticles doped by {Mo 6 I 8} 4+ metal clusters

AO Solovieva, YA Vorotnikov, KE Trifonova… - Journal of Materials …, 2016 - pubs.rsc.org
Silica nanoparticles (SNPs) doped by hexanuclear molybdenum cluster complexes
[{Mo6X8} L6] n (X= Cl, Br, or I; L= various inorganic or organic ligands) have been recently …

A comparative study of the redox and excited state properties of (n Bu 4 N) 2 [Mo 6 X 14] and (n Bu 4 N) 2 [Mo 6 X 8 (CF 3 COO) 6](X= Cl, Br, or I)

K Kirakci, P Kubát, J Langmaier, T Polívka… - Dalton …, 2013 - pubs.rsc.org
The excited-state dynamics, luminescence, and redox properties of a series of hexanuclear
molybdenum cluster complexes,(nBu4N) 2 [Mo6X14] and (nBu4N) 2 [Mo6X8 (CF3COO) …

Cationic octahedral molybdenum cluster complexes functionalized with mitochondria-targeting ligands: Photodynamic anticancer and antibacterial activities

K Kirakci, J Zelenka, M Rumlová, J Cvačka… - Biomaterials …, 2019 - pubs.rsc.org
Octahedral molybdenum cluster complexes have recently come forth as pertinent singlet
oxygen photosensitizers towards biological applications. Still, their phototoxic efficiency in …

Advances in the engineering of near infrared emitting liquid crystals and copolymers, extended porous frameworks, theranostic tools and molecular junctions using …

S Cordier, Y Molard, KA Brylev, YV Mironov… - Journal of Cluster …, 2015 - Springer
At the occasion of the fiftieth birthday of the introduction of the term 'metal atom cluster'by FA
Cotton in inorganic chemistry, it is the good time to make a review on the advances in the …

A highly luminescent hexanuclear molybdenum cluster–a promising candidate toward photoactive materials

K Kirakci, P Kubát, M Dušek, K Fejfarová… - European Journal of …, 2012 - Wiley Online Library
A new Mo6 cluster complex and its silica and polyurethane composites have been
synthesized and characterized. These materials are highly luminescent with emission above …

Water-soluble octahedral molybdenum cluster compounds Na2 [Mo6I8 (N3) 6] and Na2 [Mo6I8 (NCS) 6]: Syntheses, luminescence, and in vitro studies

K Kirakci, P Kubát, M Kučeráková, V Šícha… - Inorganica Chimica …, 2016 - Elsevier
The octahedral molybdenum cluster compounds Na 2 [Mo 6 I 8 (N 3) 6] and Na 2 [Mo 6 I 8
(NCS) 6] were synthesized and their luminescent properties and biological activity were …