Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

A review of state of the art in phosphine ligated gold clusters and application in catalysis

RH Adnan, JML Madridejos, AS Alotabi… - Advanced …, 2022 - Wiley Online Library
Atomically precise gold clusters are highly desirable due to their well‐defined structure
which allows the study of structure–property relationships. In addition, they have potential in …

Creation of High‐Performance Heterogeneous Photocatalysts by Controlling Ligand Desorption and Particle Size of Gold Nanocluster

T Kawawaki, Y Kataoka, M Hirata… - Angewandte Chemie …, 2021 - Wiley Online Library
Recently, the creation of new heterogeneous catalysts using the unique electronic/geometric
structures of small metal nanoclusters (NCs) has received considerable attention. However …

Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties

S Hossain, D Hirayama, A Ikeda, M Ishimi… - …, 2023 - Wiley Online Library
Thiolate (SR)‐protected gold nanoclusters (Aun (SR) m NCs) are a rare type of material
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …

Controlled Formation of Fused Metal Chalcogenide Nanoclusters Using Soft Landing of Gaseous Fragment Ions

H Gholipour-Ranjbar, HY Samayoa-Oviedo, J Laskin - ACS nano, 2023 - ACS Publications
The complete ligation of nanoclusters significantly reduces their chemical reactivity, catalytic
activity, and charge transfer properties. Therefore, in applications, nanoclusters are activated …

Synthesis of Ag nanoparticles-decorated CNTs via laser ablation method for the enhancement the photocatalytic removal of naphthalene from water

FS Alamro, AM Mostafa, KAA Al-Ola, HA Ahmed… - Nanomaterials, 2021 - mdpi.com
Silver nanoparticles (Ag NPs) were decorated with different amounts on the exterior walls of
carbon nanotubes (CNTs) by a laser ablation assisted method, especially in liquid media to …

Operando surface spectroscopy and microscopy during catalytic reactions: from clusters via nanoparticles to meso‐scale aggregates

G Rupprechter - Small, 2021 - Wiley Online Library
Operando characterization of working catalysts, requiring per definitionem the simultaneous
measurement of catalytic performance, is crucial to identify the relevant catalyst structure …

Toward the creation of high-performance heterogeneous catalysts by controlled ligand desorption from atomically precise metal nanoclusters

T Kawawaki, Y Kataoka, M Hirata, Y Iwamatsu… - Nanoscale …, 2021 - pubs.rsc.org
Ligand-protected metal nanoclusters controlled by atomic accuracy (ie atomically precise
metal NCs) have recently attracted considerable attention as active sites in heterogeneous …

The factors dictating properties of atomically precise metal nanocluster electrocatalysts

H Yan, H Xiang, J Liu, R Cheng, Y Ye, Y Han, C Yao - Small, 2022 - Wiley Online Library
Metal nanoparticles occupy an important position in electrocatalysis. Unfortunately, by using
conventional synthetic methodology, it is a great challenge to realize the monodisperse …

Partially Thiolated Au25 Cluster Anchored on Carbon Support via Noncovalent Ligand–Support Interactions: Active and Robust Catalyst for Aerobic Oxidation of …

K Sakamoto, S Masuda, S Takano, T Tsukuda - ACS Catalysis, 2023 - ACS Publications
Partially thiolated atomically precise Au cluster catalysts were developed by controlled
calcination of presynthesized thiolate-protected Au clusters on a porous carbon support. X …