Xanthones from fungi, lichens, and bacteria: the natural products and their synthesis

KS Masters, S Bräse - Chemical reviews, 2012 - ACS Publications
In 1961 Roberts submitted a comprehensive review in which he described the 16 naturally
occurring xanthones identified to that date, of which 5 were of fungal or lichenoid origin. 2 …

Endophytic fungi: a reservoir of antibacterials

SK Deshmukh, SA Verekar, SV Bhave - Frontiers in microbiology, 2015 - frontiersin.org
Multidrug drug resistant bacteria are becoming increasingly problematic particularly in the
under developed countries of the world. The most important microorganisms that have seen …

Absolute configuration determination by quantum mechanical calculation of chiroptical spectra: Basics and applications to fungal metabolites

S Superchi, P Scafato, M Gorecki… - Current medicinal …, 2018 - ingentaconnect.com
Background: Quantum mechanical simulations of chiroptical properties, such as electronic
circular dichroism (ECD), optical rotation (OR), and vibrational circular dichroism (VCD) …

Dinuclear metal‐prophenol catalysts: development and synthetic applications

BM Trost, CI Hung, G Mata - Angewandte Chemie International …, 2020 - Wiley Online Library
The ProPhenol ligand is a member of the chiral aza‐crown family that spontaneously forms
a bimetallic complex upon treatment with alkyl metal reagents, such as Et2Zn and Bu2Mg …

Asymmetric allylic C–H oxidation for the synthesis of chromans

PS Wang, P Liu, YJ Zhai, HC Lin, ZY Han… - Journal of the …, 2015 - ACS Publications
An enantioselective intramolecular allylic C–H oxidation to generate optically active
chromans has been accomplished under the cooperative catalysis of a palladium complex …

Role of the endogenous fungal metabolites in the plant growth improvement and stress tolerance

P Sharma, SP Singh - Fungi bio-prospects in sustainable agriculture …, 2021 - Elsevier
An endophyte is a microbe that lives inside the host plants for part of its life but does not
cause any kind of disease or infection. Plants are continuously faced with a wide range of …

Direct enantio-and diastereoselective vinylogous addition of butenolides to chromones catalyzed by Zn-prophenol

BM Trost, E Gnanamani, CA Kalnmals… - Journal of the …, 2019 - ACS Publications
We report the first enantio-and diastereoselective 1, 4-addition of butenolides to chromones.
Both α, β-and β, γ-butenolide nucleophiles are compatible with the Zn-ProPhenol catalyst …

Metabolites of endophytic fungi as novel source of biofungicide: a review

S Kumar, N Kaushik - Phytochemistry reviews, 2012 - Springer
Endophytic fungi are known to harbour compound (s) beneficial for plant health as well as
human health. Among the metabolites of agrochemical and pharmaceutical importance …

Asymmetric synthesis of chromanone lactones via vinylogous conjugate addition of butenolide to 2-ester chromones

Y Li, S Xin, R Weng, X Liu, X Feng - Chemical Science, 2022 - pubs.rsc.org
Chiral chromanone lactones are a class of natural products with important biological activity.
We report a direct diastereo-and enantioselective vinylogous conjugate addition of …

A facile enantioselective alkynylation of chromones

LG DeRatt, M Pappoppula… - Angewandte Chemie …, 2019 - Wiley Online Library
The first catalytic enantioselective alkynylation of chromones is reported. In this process,
chromones are silylated to form silyloxybenzopyrylium ions that lead to silyl enol ethers after …