Transition-metal-catalyzed, coordination-assisted C (sp3)–H functionalization has
revolutionized synthetic planning over the past few decades as the use of these directing …

In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

The various applications of hydrogen isotopes (deuterium, D, and tritium, T) in the physical
and life sciences demand a range of methods for their installation in an array of molecular …

Transition-metal catalyzed C–H activation reactions have been proven to be useful
methodologies for the assembly of synthetically meaningful molecules. This approach bears …

The exponential increase in the number of catalytic transformations that involve a metal‐
promoted activation of hitherto considered inert C− H bonds is promoting a fundamental …

An electrochemical method for the synthesis of 2-aminothiazoles via aryl ring construction
using enaminones and thioureas is reported. The cascade enamine C–H thiolation and C–N …

Conspectus The history of transition metal catalysis is heavily steeped in ligand design,
clearly demonstrating the importance of this approach. The intimate relationship between …

Rhodium (III)-catalyzed direct functionalization of C–H bonds under oxidative conditions
leading to C–C, C–N, and C–O bond formation is reviewed. Various arene substrates …

Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles | Chemical Reviews
ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Directing groups that can act as internal oxidants have recently been shown to be beneficial
in metal-catalyzed heterocycle syntheses that undergo C− H functionalization. Pursuant to …