ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics

S Vyazovkin, D Achilias, X Fernandez-Francos… - Thermochimica acta, 2022 - Elsevier
The present recommendations have been developed by the Kinetics Committee of the
International Confederation for Thermal Analysis and Calorimetry (ICTAC). The …

Control of reactions and network structures of epoxy thermosets

T Vidil, F Tournilhac, S Musso, A Robisson… - Progress in Polymer …, 2016 - Elsevier
Recent advances in macromolecular chemistry have revolutionized the way we perceive the
synthesis of polymers. Polymerization, to be modern, must be “controlled”, which usually …

Sequential curing of off-stoichiometric thiol–epoxy thermosets with a custom-tailored structure

X Fernández-Francos, AO Konuray, A Belmonte… - Polymer …, 2016 - pubs.rsc.org
A new dual-curing system based on sequential thiol–epoxy click polycondensation and
epoxy anionic homopolymerization was studied. Formulations of diglycidyl ether of …

Analysis of the reaction mechanism of the thiol–epoxy addition initiated by nucleophilic tertiary amines

AO Konuray, X Fernández-Francos, X Ramis - Polymer chemistry, 2017 - pubs.rsc.org
A kinetic model for thiol–epoxy crosslinking initiated by tertiary amines has been proposed.
The kinetic model is based on mechanistic considerations and it features the effect of the …

Electrically switchable light transmittance of epoxy-mercaptan polymer/nematic liquid crystal composites with controllable microstructures

W Shen, L Wang, T Zhong, G Chen, C Li, M Chen… - Polymer, 2019 - Elsevier
In this paper, we report the design, preparation and properties of epoxy-mercaptan
polymer/nematic liquid crystal (LC) composites with electrically switchable optical …

Design and function of thermoresponsive-ultrafast stiffening suspension formulations for 3D printing

SB Kandy, S Remke, T Ranganathan, SK Wani… - Cement and Concrete …, 2025 - Elsevier
An inability to accurately control the rate and extent of solidification of cementitious
suspensions is a major impediment to creating geometrically complex structural shapes via …

Latent curing of epoxy-thiol thermosets

AO Konuray, X Fernandez-Francos, X Ramis - Polymer, 2017 - Elsevier
Epoxy-thiol curing is a click reaction which allows quantitative yield of the end products. The
base-catalyzed reaction is rapid at low temperatures so it is most often desirable to harness …

Kinetics of multifunctional thiol-epoxy click reactions studied by differential scanning calorimetry: Effects of catalysis and functionality

K Jin, WH Heath, JM Torkelson - Polymer, 2015 - Elsevier
Isothermal reaction kinetics of thiol-epoxy (multifunctional thiol-difunctional epoxy) reactions
with and without external catalyst 1, 8-diazabicyclo [5.4. 0] undec-7-ene (DBU) were studied …

Preparation of new biobased coatings from a triglycidyl eugenol derivative through thiol-epoxy click reaction

D Guzman, X Ramis, X Fernandez-Francos… - Progress in Organic …, 2018 - Elsevier
A new triglycidyl eugenol derivative (3EPO-EU) was synthesized and characterized by
spectroscopic techniques, and used as starting monomer in the preparation of novel bio …

Preparation of click thiol-ene/thiol-epoxy thermosets by controlled photo/thermal dual curing sequence

D Guzmán, X Ramis, X Fernández-Francos, A Serra - RSC advances, 2015 - pubs.rsc.org
A new sequential two steps photo and thermal process for the preparation of click thiol-
ene/thiol-epoxy thermosets is described. Commercially available diglycidyl ether of …