Allenes are valuable organic molecules that feature unique physical and chemical
properties. They are not only often found in natural products, but also act as versatile …

Conspectus So far, over 150 natural products and pharmaceuticals containing an allene
moiety have been identified. During the last two decades, allenes have also been …

A copper-catalyzed three-component reaction of cyclobutanone oxime esters and 1, 3-
enynes in the presence of TMSCN or TMSCF3 has been developed. This mild protocol …

Many reactions involving allenyl ion species have been studied, but reactions involving
allenyl radicals are less well understood, perhaps because of the inconvenience associated …

Recent Advances and Perspectives in Transition Metal‐Catalyzed 1,4‐Functionalizations of
Unactivated 1,3‐Enynes for the Synthesis of Allenes - Fu - 2020 - Chinese Journal of Chemistry …

The different enantiomers of specific chiral molecules frequently exhibit disparate biological,
physiological, or pharmacological properties. Therefore, the efficient synthesis of single …

Allenes have proven themselves to be valuable building blocks toward complex molecular
targets, revealing novel applications in natural product synthesis, pharmaceutical chemistry …

We disclose herein the first example of merging photoredox catalysis and copper catalysis
for radical 1, 4-carbocyanations of 1, 3-enynes. Alkyl N-hydroxyphthalimide esters are …

While one-carbon central chirality of organic molecules has been recognized and
extensively studied for more than a century, far less attention has been paid to three-carbon …

The first enantioselective copper-catalyzed cyanation of propargylic C–H bonds via radical
relay was established using novel BoxOTMS ligands, providing an efficient and …