Ligand Engineering in Nickel Phthalocyanine to Boost the Electrocatalytic Reduction of CO2

K Chen, M Cao, Y Lin, J Fu, H Liao… - Advanced Functional …, 2022 - Wiley Online Library
Designing and synthesizing efficient molecular catalysts may unlock the great challenge of
controlling the CO2 reduction reaction (CO2RR) with molecular precision. Nickel …

NEXAFS spectroscopy of conjugated polymers

MM Nahid, E Gann, L Thomsen, CR McNeill - European Polymer Journal, 2016 - Elsevier
This feature article provides a general introduction to Near Edge X-ray Absorption Fine
Structure (NEXAFS) spectroscopy of conjugated polymers as well as a perspective on the …

New Advances and Opportunities in Group 15 Porphyrin Chemistry

PK Poddutoori - Dalton Transactions, 2023 - pubs.rsc.org
The chemistry of Group 15 porphyrins has been established relatively well among the main-
group porphyrins. Thus far phosphorus (III), phosphorus (V), arsenic (III), arsenic (V) …

A new class of epitaxial porphyrin metal–organic framework thin films with extremely high photocarrier generation efficiency: promising materials for all-solid-state …

J Liu, W Zhou, J Liu, Y Fujimori, T Higashino… - Journal of Materials …, 2016 - pubs.rsc.org
We demonstrate the fabrication of a new class of epitaxial porphyrin metal–organic
framework thin films whose photophysical properties can be tuned by the introduction of …

Donor–acceptor stacking arrangements in bulk and thin-film high-mobility conjugated polymers characterized using molecular modelling and MAS and surface …

SR Chaudhari, JM Griffin, K Broch, A Lesage… - Chemical …, 2017 - pubs.rsc.org
Conjugated polymers show promising properties as cheap, sustainable and solution-
processable semiconductors. A key challenge in the development of these materials is to …

Intramolecular Charge Transfer and Spin–Orbit Coupled Intersystem Crossing in Hypervalent Phosphorus (V) and Antimony (V) Porphyrin Black Dyes

JR Hamza, JK Sharma, PA Karr… - Journal of the …, 2024 - ACS Publications
Porphyrin dyes with strong push–pull type intramolecular charge transfer (ICT) character
and broad absorption across the visible spectrum are reported. This combination of …

Excited-State Charge Distribution of a Donor− π–Acceptor Zn Porphyrin Probed by N K-Edge Transient Absorption Spectroscopy

AA Cordones, CD Pemmaraju, JH Lee… - The Journal of …, 2021 - ACS Publications
Zinc porphyrin solar cell dyes with donor− π–acceptor architectures combine light absorber
(π), electron-donor, and electron-acceptor moieties inside a single molecule with atomic …

Probing adsorption interactions in metal–organic frameworks using X-ray spectroscopy

WS Drisdell, R Poloni, TM McDonald… - Journal of the …, 2013 - ACS Publications
We explore the local electronic signatures of molecular adsorption at coordinatively
unsaturated binding sites in the metal–organic framework Mg-MOF-74 using X-ray …

Antimony (+ 5) ion induced tunable intramolecular charge transfer in hypervalent antimony (v) porphyrins

N Holzer, JK Sharma, S Peterson, BJ Bayard… - Dalton …, 2022 - pubs.rsc.org
The+ 5 oxidation state of antimony induced push–pull style intramolecular charge transfer in
an elegantly designed axial dimethoxyantimony (V) porphyrin series: SbP (OMe) 2· PF6 …

Functionalized porphyrin derivatives for solar energy conversion

PA Angaridis, T Lazarides, AC Coutsolelos - Polyhedron, 2014 - Elsevier
In this review, we discuss a collection of three sets of porphyrin-based systems recently
synthesized in our group. In the first set we improve the light harvesting ability of porphyrins …