Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

Rearrangement reactions, one of the most significant transformations in organic chemistry,
play an irreplaceable role in improving synthetic efficiency and molecular complexity …

The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …

Conspectus Alkenes are ubiquitous in natural products and are extensively used as
synthetic feedstocks in multiple fields including organic synthesis, medicinal chemistry, and …

One of the simplest organic functional groups, the alkyne, offers a broad canvas for the
design of cascade transformations in which up to three new bonds can be added to each of …

Light-driven utilization of CO2 in organic synthesis is highly attractive because it mimics
nature. However, such transformations are mainly limited to the incorporation of only a …

In recent years, radical C–C bond cleavage reactions have been increasingly understood
and used to perform transformations that complement traditional ionic processes. However …

Ketyl radicals are valuable reactive intermediates for synthesis and are used extensively to
construct complex, functionalized products from carbonyl substrates. Single electron transfer …

C (sp3) radicals (R˙) are of broad research interest and synthetic utility. This review collects
some of the most recent advancements in photocatalytic R˙ generation and highlights …

The remote radical migration strategy has gained considerable momentum. During the past
three years, we have witnessed the rapid development of sustainable and practical C–C and …