Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Electrochemical transformations catalyzed by cytochrome P450s and peroxidases

N Kumar, J He, JF Rusling - Chemical Society Reviews, 2023 - pubs.rsc.org
Cytochrome P450s (Cyt P450s) and peroxidases are enzymes featuring iron heme cofactors
that have wide applicability as biocatalysts in chemical syntheses. Cyt P450s are a family of …

Quantification of hydrogen peroxide by electrochemical methods and electron spin resonance spectroscopy

R Gulaboski, V Mirčeski, R Kappl… - Journal of The …, 2019 - iopscience.iop.org
Reactive oxygen species (ROS) exhibit different spatial and temporal distributions as well as
concentrations in-and outside the cell, thereby functioning as signaling or pathogen …

Specific buffer effects on the intermolecular interactions among protein molecules at physiological pH

A Salis, L Cappai, C Carucci, DF Parsons… - The Journal of …, 2020 - ACS Publications
BSA and lysozyme molecular motion at pH 7.15 is buffer-specific. Adsorption of buffer ions
on protein surfaces modulates the protein surface charge and thus protein–protein …

The Influence of pH and Electrolyte Concentration on Fractional Protonation and CO2 Reduction Activity in Polymer-Encapsulated Cobalt Phthalocyanine

TL Soucy, WS Dean, KE Rivera Cruz… - The Journal of …, 2023 - ACS Publications
Polymer-encapsulated cobalt phthalocyanine (CoPc) is a model system for studying how
polymer–catalyst interactions in electrocatalytic systems influence performance for the CO2 …

High electrolyte concentration effect on enzymatic oxygen reduction

V Saska, U Contaldo, I Mazurenko, A de Poulpiquet… - …, 2023 - Elsevier
The nature, the composition and the concentration of electrolytes is essential for
electrocatalysis involving redox enzymes. Here, we discuss the effect of various electrolyte …

The melting curves of calf thymus-DNA are buffer specific

M Mura, C Carucci, FC Marincola, M Monduzzi… - Journal of Colloid and …, 2023 - Elsevier
The specific effects of salts (strong electrolytes) on biomolecular properties have been
investigated for more than a century. By contrast, the specific role of pH buffers (weak …

Control of carbon monoxide dehydrogenase orientation by site-specific immobilization enables direct electrical contact between enzyme cofactor and solid surface

SS Reginald, H Lee, N Fazil, B Sharif, M Lee… - Communications …, 2022 - nature.com
Controlling the orientation of redox enzymes on electrode surfaces is essential in the
development of direct electron transfer (DET)-based bioelectrocatalytic systems. The …

Washing-free displacement immunosensor for cortisol in human serum containing numerous interfering species

P Nandhakumar, AMJ Haque, NS Lee… - Analytical …, 2018 - ACS Publications
Simple and sensitive competitive immunosensors for small molecules are difficult to obtain,
especially in serum containing numerous interfering species (ISs) with different …

[HTML][HTML] Cation and buffer specific effects on the DNA-lipid interaction

M Mura, B Humphreys, J Gilbert, A Salis… - Colloids and Surfaces B …, 2023 - Elsevier
Abstract Knowledge of DNA-lipid layer interactions is key for the development of biosensors,
synthetic nanopores, scaffolds, and gene-delivery systems. These interactions are strongly …