Advanced functional luminescent metallomesogens: the key role of the metal center

C Cuerva, M Cano, C Lodeiro - Chemical Reviews, 2021 - ACS Publications
The use of liquid crystals for the fabrication of displays incorporated in technological devices
(TVs, calculators, screens of eBook's, tablets, watches) demonstrates the relevance that …

Over the LEC rainbow: Colour and stability tuning of cyclometallated iridium (III) complexes in light-emitting electrochemical cells

CE Housecroft, EC Constable - Coordination Chemistry Reviews, 2017 - Elsevier
This review surveys the design of cyclometallated iridium (III) complexes for applications in
light-emitting electrochemical cells (LECs). Typical iridium-containing ionic transition metal …

Lessons learned in tuning the optoelectronic properties of phosphorescent iridium (III) complexes

AF Henwood, E Zysman-Colman - Chemical Communications, 2017 - pubs.rsc.org
This perspective illustrates our approach in the design of heteroleptic cationic iridium (III)
complexes for optoelectronic applications, especially as emitters in electroluminescent …

[HTML][HTML] Chemosensors based on N-heterocyclic dyes: Advances in sensing highly toxic ions such as CN− and Hg 2+

MC Ríos, NF Bravo, CC Sánchez, J Portilla - RSC advances, 2021 - pubs.rsc.org
CN− and Hg2+ ions are harmful to both the environment and human health, even at trace
levels. Thus, alternative methods for their detection and quantification are highly desirable …

[HTML][HTML] Luminescent Copper (I) complexes as promising materials for the next generation of energy-saving OLED devices

LP Ravaro, KPS Zanoni, ASS de Camargo - Energy Reports, 2020 - Elsevier
The increasing demand for electrical energy by a longer living and increasing population
justifies the search for new, more efficient lighting systems. In this context, organo-metallic …

Cyclometalated Ir–Zr metal–organic frameworks as recyclable visible-light photocatalysts for sulfide oxidation into sulfoxide in water

LQ Wei, BH Ye - ACS applied materials & interfaces, 2019 - ACS Publications
Aerobic photo-oxidation of sulfide into sulfoxide in water is of great interest in green
chemistry. In this study, three highly stable Ir (III)–Zr (IV) metal–organic frameworks (Ir–Zr …

[HTML][HTML] Cyclometalated iridium (III) chelates—a new exceptional class of the electrochemiluminescent luminophores

A Kapturkiewicz - Analytical and Bioanalytical Chemistry, 2016 - Springer
Recent development of the phosphorescent cyclometalated iridium (III) chelates has
enabled, due to their advantageous electrochemical and photo-physical properties …

Recent advances in synthesis of molecular heteroleptic osmium and iridium phosphorescent emitters

ML Buil, MA Esteruelas… - European journal of …, 2021 - Wiley Online Library
The application of new procedures of organometallic synthesis based on alternative starting
complexes has given rise to a significant enhancement in the preparation of osmium (IV) …

Two Synthetic Tools to Deepen the Understanding of the Influence of Stereochemistry on the Properties of Iridium (III) Heteroleptic Emitters

JC Babón, PLT Boudreault, MA Esteruelas… - Inorganic …, 2023 - ACS Publications
Two complementary procedures are presented to prepare cis-pyridyl-iridium (III) emitters of
the class [3b+ 3b+ 3b′] with two orthometalated ligands of the 2-phenylpyridine type (3b) …

Highly fluorinated Ir (III)–2, 2′: 6′, 2 ″-terpyridine–phenylpyridine–X complexes via selective C–F activation: Robust photocatalysts for solar fuel generation and …

JA Porras, IN Mills, WJ Transue… - Journal of the American …, 2016 - ACS Publications
A series of fluorinated Ir (III)–terpyridine–phenylpyridine–X (X= anionic monodentate ligand)
complexes were synthesized by selective C–F activation, whereby perfluorinated …