Lactones: Classification, synthesis, biological activities, and industrial applications

SK Sartori, MAN Diaz, G Diaz-Muñoz - Tetrahedron, 2021 - Elsevier
This review summarizes the current knowledge on lactones, a class of biologically active
natural products isolated from a wide range of living organisms. Butenolide, 5, 6 …

Secondary metabolites from hypocrealean entomopathogenic fungi: novel bioactive compounds

L Zhang, OE Fasoyin, I Molnár, Y Xu - Natural Product Reports, 2020 - pubs.rsc.org
Covering: 2014 up to the third quarter of 2019 Entomopathogens constitute a unique,
specialized trophic subgroup of fungi, most of whose members belong to the order …

Applications of Sharpless asymmetric epoxidation in total synthesis

MM Heravi, TB Lashaki, N Poorahmad - Tetrahedron: Asymmetry, 2015 - Elsevier
This report presents the applications of enantioselective epoxidation of prochiral allylic
alcohols, so called 'Sharpless asymmetric epoxidation', which is frequently referred as …

Applications of sharpless asymmetric dihydroxylation in the total synthesis of natural products

MM Heravi, V Zadsirjan, M Esfandyari… - Tetrahedron: Asymmetry, 2017 - Elsevier
Sharpless asymmetric dihydroxylation involves the reaction of an alkene with osmium
tetroxide in the presence of a chiral quinine ligand to form an optically active vicinal diol …

The synthesis of structurally diverse macrocycles by successive ring expansion

C Kitsiou, JJ Hindes, P I'Anson… - Angewandte Chemie …, 2015 - Wiley Online Library
Structurally diverse macrocycles and medium‐sized rings (9–24 membered scaffolds, 22
examples) can be generated through a telescoped acylation/ring‐expansion sequence …

Applications of Yamaguchi method to esterification and macrolactonization in total synthesis of bioactive natural products

S Majhi - ChemistrySelect, 2021 - Wiley Online Library
Yamaguchi protocol provides functionalized esters regioselectively from carboxylic acids
and alcohols employing 2, 4, 6‐trichlorobenzoyl chloride as the condensation reagent in the …

[PDF][PDF] Asymmetric Synthesis of Allylsilanes by the Borylation of Lithiated Carbamates: Formal Total Synthesis of (−)‐Decarestrictine D

M Binanzer, GY Fang, VK Aggarwal - Angewandte Chemie, 2010 - bristol.ac.uk
Chiral allylsilanes are highly valuable nucleophiles in stereoselective organic synthesis
because of the multitude of asymmetric transformations that they can undergo.[1] For …

Applications of the Wittig Reaction on the Synthesis of Natural and Natural‐Analogue Heterocyclic Compounds

DHA Rocha, DCGA Pinto… - European Journal of …, 2018 - Wiley Online Library
More than sixty years after its discovery, the Wittig reaction still is a powerful tool to create
carbon–carbon double bonds. The large diversity of high‐yielding and stereoselective …

Tricrilactones A–H, Potent Antiosteoporosis Macrolides with Distinctive Ring Skeletons from Trichocladium crispatum, an Alpine Moss‐Associated Fungus

WB Han, YJ Zhai, R Zhang, XS Gong, JQ Li… - Angewandte …, 2023 - Wiley Online Library
Abstract Tricrilactones A–H (1–8), a new family of oligomeric 10‐membered macrolides
featuring collectively five unique ring skeletons, were isolated from a hitherto unexplored …

Bioactive Nonanolide Derivatives Isolated from the Endophytic Fungus Cytospora sp.

S Lu, P Sun, T Li, T Kurtán, A Mándi… - The Journal of …, 2011 - ACS Publications
Cytospolides F–Q (6–17) and decytospolides A and B (18 and 19), 14 unusual nonanolide
derivatives, were isolated from Cytospora sp., an endophytic fungus from Ilex canariensis …