Beyond charge balance: counter‐cations in polyoxometalate chemistry

A Misra, K Kozma, C Streb… - Angewandte Chemie …, 2020 - Wiley Online Library
Polyoxometalates (POMs) are molecular metal‐oxide anions applied in energy conversion
and storage, manipulation of biomolecules, catalysis, as well as materials design and …

Design and synthesis of polyoxometalate-framework materials from cluster precursors

L Vilà-Nadal, L Cronin - Nature Reviews Materials, 2017 - nature.com
Inorganic oxide materials are used in semiconductor electronics, ion exchange, catalysis,
coatings, gas sensors and as separation materials. Although their synthesis is well …

Surface-exposed silver nanoclusters inside molecular metal oxide cavities

K Yonesato, D Yanai, S Yamazoe, D Yokogawa… - Nature Chemistry, 2023 - nature.com
The surfaces of metal nanoclusters, including their interface with metal oxides, exhibit a high
reactivity that is attractive for practical purposes. This high reactivity, however, has also …

Ce-mediated molecular tailoring on gigantic polyoxometalate {Mo132} into half-closed {Ce11Mo96} for high proton conduction

XX Li, CH Li, MJ Hou, B Zhu, WC Chen, CY Sun… - Nature …, 2023 - nature.com
Precise synthesis of polyoxometalates (POMs) is important for the fundamental
understanding of the relationship between the structure and function of each building motif …

The surface chemistry of metal oxide clusters: From metal–organic frameworks to minerals

D Yang, M Babucci, WH Casey, BC Gates - ACS Central Science, 2020 - ACS Publications
Many metal–organic frameworks (MOFs) incorporate nodes that are small metal oxide
clusters. Some of these MOFs are stable at high temperatures, offering good prospects as …

Polyoxometalate-based all-inorganic open frameworks

XK Lian, HB Chen, YD Lin, XX Li, ST Zheng - Coordination Chemistry …, 2023 - Elsevier
Polyoxometalates (POMs) are an intriguing class of compounds that have been extensively
studied due to their unique structures and diverse properties. In the past years, the synthesis …

Polyoxometalate-cyclodextrin supramolecular entities for real-time in situ monitoring of dopamine released from neuroblastoma cells

SS Shetty, B Moosa, L Zhang, B Alshankiti… - Biosensors and …, 2023 - Elsevier
Optimized and sensitive biomarker detection has recently been shown to have a critical
impact on quality of diagnosis and medical care options. In this research study …

Polyoxometalate-based metal–organic frameworks for selective oxidation of aryl alkenes to aldehydes

Y Ma, H Peng, J Liu, Y Wang, X Hao, X Feng… - Inorganic …, 2018 - ACS Publications
Polyoxometalates (POMs) show considerable catalytic performance toward the selective
oxidation of alkenes to aldehydes, which is commercially valuable for the production of …

Heteroatom-modulated assembly of hexalanthanoid-containing polyoxometalate-based coordination networks

ZX Yang, XW Liang, D Lin, Q Zheng, Y Huo - Inorganic Chemistry, 2023 - ACS Publications
Two series of lanthanoid (Ln)-containing polyoxometalates (POMs){[Ln6 (ampH) 4 (H2O) 24–
n (ampH2) n (PW11O39) 2]· 21H2O (Ln= Tb, n= 0 (1), Ln= Er, n= 1 (2)) and K2 [Ln6 (ampH) …

Self-assembled supramolecular polyoxometalate hybrid architecture as a multifunctional oxidation catalyst

L Ni, H Li, H Xu, C Shen, R Liu, J Xie… - … applied materials & …, 2019 - ACS Publications
Polyoxometalates (POMs) are widely applied as tuneable and versatile catalysts for a variety
of oxidation reactions in an aqueous/organic two-phase system. However, the practical …