Complexes of transition metals with heavy analogs of carbenes (tetrylenes) as ligands have
been studied now for some 40 years. The current review attempts to provide an overview …

Metal carbonyl complexes possess among the most storied histories of any compound class
in organometallic chemistry. Nonetheless, these old dogs continue to be taught new tricks. In …

Asymmetric hydrogen atom transfer (HAT) represents arguably one of the most
straightforward access to the significant chiral tertiary carbon centers, however, remains a …

The reactions of [ArE (Cl)] 2 (E= Ge, Sn; Ar=− C6H3-2, 6-(C6H3-2, 6-i Pr2) 2 (ArPri4),− C6H3-
2, 6-(C6H2-2, 4, 6-i Pr3) 2 (ArPri6)) with K [(η5-C5H5) Fe (CO) 2] afforded the deep green …

In this report, the catalytic potential of chalcogen-stabilized iron carbonyl clusters [Fe3E2
(CO) 9 (E= S, Se, Te)] for the photolytic hydration of alkynes has been explored. The iron …

Reactions of cyclopentadienyl transition-metal halide complexes [Cp* Mo (CO) 3Cl], 1, and
[CpFe (CO) 2I], 2,(Cp= C5H5; Cp*= η5-C5Me5) with borate ligands are reported. Treatment …

The reaction of Pt (COD) 2 with one equivalent of tri-tert-butylstannane, But3SnH, at room
temperature yields Pt (SnBut3)(COD)(H)(3) in quantitative yield. In the presence of excess …

This review provides an overview of some aspects, including most recent studies, regarding
the C–H bond activation/functionalization of saturated or unsaturated hydrocarbons as well …

Simultaneous framework incorporation of heavy metal ions such as Ru (III) and Sn (IV) into
aluminophosphate architectures generates novel bimetallic active sites, which facilitate …

The reaction of dipotassio‐tetrasilan‐1, 4‐diide (4) with anhydrous SnCl2 at low temperature
results in the formation of a five‐membered cyclic potassio chlorostannate (II)([(18‐C‐6) …