The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …

Organophosphines have garnered attention from many avenues ranging from agriculture to
fine chemicals. One‐time use of phosphate resources has made sustainable use of …

Despite significant advances, metal‐catalyzed hydrophosphination has ample room for
discovery, growth, and development. Many of the key successes in metal‐catalyzed …

Use of organolanthanides in the catalytic intermolecular hydrophosphination and
hydroamination of multiple C–C bonds - Dalton Transactions (RSC Publishing) DOI:10.1039/C6DT03913H …

A range of symmetric amidinate ligands RAmAr (R is backbone substituent, Ar is N
substituent) have been investigated for their ability to stabilize calcium hydride complexes of …

The large alkaline earths (Ae), calcium, strontium and barium, have in the past 15 years
yielded a brand new generation of heteroleptic molecular catalysts for the production of fine …

A series of Ln (II) and Ca (II) bis (alkyl) complexes with bulky benzhydryl ligands,[(pt Bu-
C6H4) 2CH] 2M (L n)(M= Sm, L= DME, n= 2 (1); M= Sm, Yb, Ca, L= TMEDA, n= 1 (2, 3, 4) …

Redistribution of primary silanes through C–Si and Si–H bond cleavage and reformation
provides a straightforward synthesis of secondary silanes, but the poor selectivity and low …

The first example of intermolecular hydrophosphination of styrene, 2‐vinylpyridine and
phenylacetylene with PH3 catalyzed by bis‐(amido) complexes [(Me3Si) 2N] 2M (NHC) 2 …

Ln( ii ) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising
catalysts for olefin hydrophosphination - Chemical Communications (RSC Publishing) …