An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered. The examined …
A versatile approach for the alkynylation of a variety of aliphatic hydrogen donors, including alkanes, is reported. We used tetrabutylammonium decatungstate as photocatalyst to …
PF Chen, DS Li, WT Ou, F Xue, HP Deng - Organic Letters, 2023 - ACS Publications
1, 3-Functionalized cyclobutane structural motifs are ubiquitous in natural products and pharmaceuticals. Photoinduced alkylation of bicyclo [1.1. 0] butanes (BCBs) offers a step …
H Zheng, Y Fan, AL Blenko, W Lin - Journal of the American …, 2023 - ACS Publications
Herein, we report the synthesis of a bifunctional photocatalyst, Zr-OTf-EY, through sequential modifications of metal cluster nodes in a metal–organic layer (MOL). With eosin Y and strong …
Presented is a light-promoted C–C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst. This …
Y Li, Y Kuninobu - Advanced Synthesis & Catalysis, 2023 - Wiley Online Library
We developed a site‐selective intermolecular C (sp3)− H alkylation of saccharides with electron‐deficient alkenes using photocatalysis by anthraquinone and tetrabutylammonium …
A Jorea, B Bassetti, K Gervasoni, S Protti… - Advanced Synthesis …, 2023 - Wiley Online Library
The hydroalkylation of nitroalkenes and β‐nitroacrylates via a photocatalytic strategy has been optimised under both batch and continuous flow conditions. This target has been …
Z Liu, M Li, G Deng, W Wei, P Feng, Q Zi, T Li… - Chemical …, 2020 - pubs.rsc.org
A unique C (sp3)–H/C (sp3)–H dehydrocoupling of N-benzylimines with saturated heterocycles is described. Using super electron donor (SED) 2-azaallyl anions and aryl …
J Inoa, M Patel, G Dominici, R Eldabagh… - The Journal of …, 2020 - ACS Publications
A highly efficient benzylic hydroperoxidation has been realized through a visible-light- induced Csp3–H activation. We believe that this reaction undergoes a direct HAT …