[HTML][HTML] Unusual aspects of charge regulation in flexible weak polyelectrolytes

PM Blanco, CF Narambuena, S Madurga, F Mas… - Polymers, 2023 - mdpi.com
This article reviews the state of the art of the studies on charge regulation (CR) effects in
flexible weak polyelectrolytes (FWPE). The characteristic of FWPE is the strong coupling of …

Charge regulation of polyelectrolyte gels: Swelling transition

B Zheng, Y Avni, D Andelman, R Podgornik - Macromolecules, 2023 - ACS Publications
We study the effects of charge-regulated acid/base equilibrium on the swelling of
polyelectrolyte gels by considering a combination of the Poisson–Boltzmann theory and a …

Explaining Giant Apparent Shifts in Weak Polyelectrolyte Brushes

D Beyer, P Košovan, C Holm - Physical Review Letters, 2023 - APS
Recent experiments on weak polyelectrolyte brushes found marked shifts in the effective p K
a that are linear in the logarithm of the salt concentration. Comparing explicit-particle …

Simulations explain the swelling behavior of hydrogels with alternating neutral and weakly acidic blocks

D Beyer, P Košovan, C Holm - Macromolecules, 2022 - ACS Publications
We used computer simulations to study the equilibrium swelling of weak (pH-responsive)
polyelectrolyte hydrogels as a function of pH and salt concentration in a supernatant …

Unexpected Two-Stage Swelling of Weak Polyelectrolyte Brushes with Divalent Counterions

D Beyer, C Holm - ACS Macro Letters, 2024 - ACS Publications
We use particle-based, coarse-grained simulations to study the influence of divalent
counterions on a weak polyelectrolyte brush. Our simulations show a profound influence of …

Edible hydrogels with shrinkage tolerance in acids and stomach-friendly mechanical moduli

J Huang, Z Zhang, H Jiang - Applied Materials Today, 2023 - Elsevier
Healthcare devices for the human body have seen continuous evolution, from external wear
to wearables, and now to entirely concealed placements. The gastrointestinal (GI) tract offers …

Polyelectrolyte Gels: Swelling and Deswelling upon Nonlinear Deformations

Z Wang, Y Tian, AV Dobrynin - Macromolecules, 2023 - ACS Publications
Polyelectrolyte gels, made by crosslinking of ion-containing polymers, showcase
extraordinary swelling capabilities, with their volumes expanding up to 100 times in salt-free …

Sequestration of Small Ions and Weak Acids and Bases by a Polyelectrolyte Complex Studied by Simulation and Experiment

R Stano, JJ van Lente, S Lindhoud… - Macromolecules, 2024 - ACS Publications
Mixing of oppositely charged polyelectrolytes can result in phase separation into a polymer-
poor supernatant and a polymer-rich polyelectrolyte complex (PEC). We present a new …

Synthesis of Raspberry-like Nanoparticles via Surface Grafting of Positively Charged Polyelectrolyte Brushes: Colloidal Stability and Surface Properties

BS Aldakkan, N Chalmpes, G Qi, MA Hammami… - Langmuir, 2024 - ACS Publications
A method to synthesize stable, raspberry-like nanoparticles (NPs), using surface grafting of
poly (glycidyl methacrylate)(PGMA) brushes on a polystyrene (PS) core with varying grafting …

Core–shell nanogels: the effects of morphology, electro-and magnetostatic interactions

AB Dobroserdova, ES Minina, PA Sánchez, CN Likos… - Soft Matter, 2024 - pubs.rsc.org
We study the influence of core–shell morphology on the structural characteristics of
nanogels. Using computer simulations, we examine three different types of systems …