Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

Diverse uses of the reaction of frustrated Lewis pair (FLP) with hydrogen

DW Stephan - Journal of the American Chemical Society, 2021 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs) emerged from the discovery
that H2 can be reversibly activated by combinations of sterically encumbered main group …

The critical impacts of ligands on heterogeneous nanocatalysis: A review

L Lu, S Zou, B Fang - ACS Catalysis, 2021 - ACS Publications
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …

Guidelines to achieving high selectivity for the hydrogenation of α, β-unsaturated aldehydes with bimetallic and dilute alloy catalysts: a review

M Luneau, JS Lim, DA Patel, ECH Sykes… - Chemical …, 2020 - ACS Publications
Selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols is a
challenging class of reactions, yielding valuable intermediates for the production of …

Recent advances in the use of nitrogen-doped carbon materials for the design of noble metal catalysts

JL Fiorio, MAS Garcia, ML Gothe, D Galvan… - Coordination Chemistry …, 2023 - Elsevier
Noble metals nanoparticles (NPs) and single atoms (SAs) supported on nitrogen-doped
carbon (NC) materials display remarkable activity and selectivity in a wide variety of …

Strategies to break linear scaling relationships

J Pérez-Ramírez, N López - Nature Catalysis, 2019 - nature.com
The search for new catalytic materials has relied on highly time-and human-resource-
consuming procedures. The appearance of theoretical methods that employ density …

H2 Oxidation over Supported Au Nanoparticle Catalysts: Evidence for Heterolytic H2 Activation at the Metal–Support Interface

T Whittaker, KBS Kumar, C Peterson… - Journal of the …, 2018 - ACS Publications
Water adsorbed at the metal–support interface (MSI) plays an important role in multiple
reactions. Due to its importance in CO preferential oxidation (PrOx), we examined H2 …

Microenvironment of MOF channel coordination with Pt NPs for selective hydrogenation of unsaturated aldehydes

W Zhang, W Shi, W Ji, H Wu, Z Gu, P Wang, X Li… - ACS …, 2020 - ACS Publications
Surface and interface states of noble metal nanoparticles (MNPs), closely related to the
catalytic performance, have been of great concern to academics in the field of catalysis. The …

Strategies to improve hydrogen activation on gold catalysts

N Dimitratos, G Vilé, S Albonetti, F Cavani… - Nature Reviews …, 2024 - nature.com
Catalytic reactions involving molecular hydrogen are at the heart of many transformations in
the chemical industry. Classically, hydrogenations are carried out on Pd, Pt, Ru or Ni …