Unusually Chemoselective Photocyclization of 2-(Hydroxyimino) aldehydes to Cyclobutanol Oximes: Synthetic, Stereochemical, and Mechanistic Aspects

A Di Sabato, F D'Acunzo, D Filippini… - The Journal of …, 2022 - ACS Publications
Photocyclization of carbonyl compounds (known as the Norrish–Yang reaction) to yield
cyclobutanols is, in general, accompanied by fragmentation reactions. The latter are …

Influence of nanoaggregation routes on the structure and thermal behavior of multiple-stimuli-responsive micelles from block copolymers of oligo (ethylene glycol) …

I Antignano, F D'Acunzo, D Arena, S Casciardi… - Langmuir, 2022 - ACS Publications
In this work, we compare nanoaggregation driven by pH-induced micellization (PIM) and by
the standard solvent displacement (SD) method on a series of pH-, light-, and …

[HTML][HTML] Hybrid Copper-Polyelectrolyte nanoaggregates obtained with smart block copolymers based on 4-[(hydroxyimino) aldehyde] butyl methacrylate (HIABMA) in …

I Antignano, S Casciardi, F D'Acunzo, A Del Giudice… - Polymer, 2024 - Elsevier
The AB multi-stimuli-responsive block copolymer pTEGMA-b-pHIABMA (TEGMA: tetra
(ethyleneglycol) methyl ether methacrylate; HIABMA: 4-[(hydroxyimino) aldehyde] butyl …

Click‐Connected 2‐(Hydroxyimino) aldehydes for the Design of UV‐Responsive Functional Molecules

F D'Acunzo, L Carbonaro, AD Cort… - European Journal of …, 2021 - Wiley Online Library
Click chemistry is used to functionalize simple lipophilic and water‐soluble molecules, a
complex PEGylated phospholipid (DSPE‐PEG2000), and two benzylic substrates with the 2 …

Photoexcitation of Aldehyde derivatives to access chiral added value products

A DI SABATO - 2023 - iris.uniroma1.it
A renewed interest is recently experienced in synthetic photochemical processes thanks to
the availability of different light sources and, above all, for they extraordinary potential for the …

Theoretical studies of conformational analysis and intramolecular dynamic phenomena

I Alkorta, J Elguero - Structural Chemistry, 2019 - Springer
This review reports our computational studies of a variety of topics related to conformational
analyses and intramolecular dynamic phenomena. Single and double bonds, open and ring …

Preparation method of acrylic ester compound

JE Kim, WT Lim, Y Kim, W Choi - US Patent 11,028,038, 2021 - Google Patents
The present disclosure relates to a preparation method of an acrylic ester compound. The
preparation method of an acrylic ester compound according to the present disclosure …

Synthesis and characterization of novel Methacrylates bearing A 2 (Hydroxymino) Aldehyde group and their copolymers

M Nardi - 2018 - iris.uniroma1.it
In the last few decades,“smart” polymers have gained an increasing attention in the scientific
community thanks to their large use in several applications, such as drug delivery, sensors …