Bifurcated halogen bonding involving diaryliodonium cations as iodine (III)-based double-σ-hole donors

IS Aliyarova, DM Ivanov, NS Soldatova… - Crystal Growth & …, 2021 - ACS Publications
Three diaryliodonium tetrachloroaurates (III),[Ar1IAr2][AuCl4](Ar1/Ar2= Ph/Ph (1), Ph/Mes
(2), o-(C6H4) 2 (3)), were obtained as solids (62–80%) by the metathetical reaction of …

One-and two-dimensional iodine-rich iodobismuthate (III) complexes: structure, optical properties, and features of halogen bonding in the solid state

SA Adonin, AN Usoltsev, AS Novikov… - Inorganic …, 2020 - ACS Publications
Reactions of BiI3, I2, and iodide salts of two different pyridinum cations result in the
formation of the novel iodine-rich iodobismuthates (III)(1, 3-MePy) 4 {[Bi4I16](I2)}(1) and (1 …

Supramolecular Assembly of Metal Complexes by (Aryl)I⋅⋅⋅d [PtII] Halogen Bonds

EA Katlenok, M Haukka, OV Levin… - … A European Journal, 2020 - Wiley Online Library
The theoretical data for the half‐lantern complexes [{Pt ()(μ‐)} 2][1–3; is cyclometalated 2‐Ph‐
benzothiazole; is 2‐SH‐pyridine (1), 2‐SH‐benzoxazole (2), 2‐SH‐tetrafluorobenzothiazole …

Recognition of the π-hole donor ability of iodopentafluorobenzene–a conventional σ-hole donor for crystal engineering involving halogen bonding

AA Eliseeva, DM Ivanov, AS Novikov, VY Kukushkin - CrystEngComm, 2019 - pubs.rsc.org
Iodopentafluorobenzene (IPFB or PhFI) was co-crystallized with tetra (n-butyl) ammonium
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …

Semicoordination bond breaking and halogen bond making change the supramolecular architecture of metal-containing aggregates

LE Zelenkov, DM Ivanov, EK Sadykov… - Crystal Growth & …, 2020 - ACS Publications
The complex [Ni (S2COEt) 2](1) and 1, 4-diiodotertafluorobenzene (1, 4-FIB) or 1, 3, 5-
triiodotrifluorobenzene (1, 3, 5-FIB) were cocrystallized to form solid adducts 1· 2 (1, 4-FIB) …

Reverse Sandwich Structures from Interplay between Lone Pair−π-Hole Atom-Directed C···dz2[M] and Halogen Bond Interactions

SV Baykov, SI Filimonov, AV Rozhkov… - Crystal Growth & …, 2019 - ACS Publications
4-Bromo-and 4-iodo-5-nitrophthalonitriles (BNPN and INPN, respectively) were
cocrystallized with the metal acetylacetonates [M (acac) 2](M= Pd (1), Pt (2)) to give the three …

Halogen bonding involving palladium (II) as an XB acceptor

EA Katlenok, AV Rozhkov, OV Levin… - Crystal Growth & …, 2020 - ACS Publications
The half-lantern PdII2 complexes trans-(O, C)-[Pd (ppz)(μ-O∩ N)] 2 (1) and trans-(E, N)-[Pd
(ppz)(μ-E∩ N)] 2 (E∩ N is a deprotonated 2-substituted pyridine; E= S (2), Se (3); Hppz= 1 …

Iridium Complexes with BIAN-Type Ligands: Synthesis, Structure and Redox Chemistry

NF Romashev, IV Bakaev, VI Komlyagina… - International Journal of …, 2023 - mdpi.com
A series of iridium complexes with bis (diisopropylphenyl) iminoacenaphtene (dpp-bian)
ligands,[Ir (cod)(dpp-bian) Cl](1),[Ir (cod)(NO)(dpp-bian)](BF4) 2 (2) and [Ir (cod)(dpp …

Inorganic–organic {d z2-M II S 4}⋯ π-hole stacking in reverse sandwich structures: the case of cocrystals of group 10 metal dithiocarbamates with electron-deficient …

LE Zelenkov, AA Eliseeva, SV Baykov… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Cocrystallization of the dithiocarbamate complexes [M (S2CNEt2) 2](M= Ni 1, Pd 2, Pt 3) and
X-substituted perfluoroarenes (X= I, Br; 1, 2-dibromoperfluorobenzene FBrB and 1, 2 …

Highly polar stacking interactions wrap inorganics in organics: lone-pair–π-hole interactions between the PdO 4 core and electron-deficient arenes

YV Torubaev, IV Skabitsky, AV Rozhkov… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Cocrystallization of the palladium acetate cluster Pd3 (OAc) 6 (abbreviated as [Pd3]) with
electron-deficient iodine (I)-based perfluoroarenes (ArFI: iodopentafluorobenzene, 4 …