Triple ionic–electronic conducting oxides for next-generation electrochemical devices
Triple ionic–electronic conductors (TIECs) are materials that can simultaneously transport
electronic species alongside two ionic species. The recent emergence of TIECs provides …
electronic species alongside two ionic species. The recent emergence of TIECs provides …
Emerging computational and machine learning methodologies for proton-conducting oxides: materials discovery and fundamental understanding
This review presents computational and machine learning methodologies developed during
a 5-year research project on proton-conducting oxides. The main goal was to develop …
a 5-year research project on proton-conducting oxides. The main goal was to develop …
Proton uptake into the protonic cathode material BaCo0. 4Fe0. 4Zr0. 2O3-δ and comparison to protonic electrolyte materials
R Zohourian, R Merkle, J Maier - Solid State Ionics, 2017 - Elsevier
Proton uptake in mixed-conducting cathode materials is of particular interest as it allows the
oxygen reduction reaction to proceed via the bulk path in proton conducting ceramic fuel …
oxygen reduction reaction to proceed via the bulk path in proton conducting ceramic fuel …
Hydration entropy of BaZrO 3 from first principles phonon calculations
TS Bjørheim, EA Kotomin, J Maier - Journal of Materials Chemistry A, 2015 - pubs.rsc.org
The impact of phonons on the hydration and defect thermodynamics of undoped and
acceptor (Sc, In, Y and Gd) doped BaZrO3 is addressed by means of first principles …
acceptor (Sc, In, Y and Gd) doped BaZrO3 is addressed by means of first principles …
The pivotal role of the dopant choice on the thermodynamics of hydration and associations in proton conducting BaCe 0.9 X 0.1 O 3− δ (X= Sc, Ga, Y, In, Gd and Er)
The choice of acceptor has been demonstrated to result in distinctly different hydration
properties in proton conducting perovskites such as BaZrO3 and BaCeO3 and may as such …
properties in proton conducting perovskites such as BaZrO3 and BaCeO3 and may as such …
On the relationship between chemical expansion and hydration thermodynamics of proton conducting perovskites
In this contribution, we determine the compositional dependence of the chemical expansion
and entropy of hydration of the proton conducting perovskites BaZrO3, BaSnO3, BaCeO3 …
and entropy of hydration of the proton conducting perovskites BaZrO3, BaSnO3, BaCeO3 …
A high-temperature electrochemical sensor based on CaZr0.95Sc0.05O3–δ for humidity analysis in oxidation atmospheres
AS Kalyakin, JG Lyagaeva, AY Chuikin… - Journal of Solid State …, 2019 - Springer
A way of in situ water vapor partial pressure determination in oxidizing atmospheres and
high temperatures is proposed in this work, utilizing a new and simple amperometric-type …
high temperatures is proposed in this work, utilizing a new and simple amperometric-type …
Conductivities and transport properties of Ca (Zr/Hf) 0.9 Sc0. 1O2. 95
W Huang, Y Li, H Lu, Y Ding, Y Liu - Ceramics International, 2021 - Elsevier
Doped CaZrO 3 proton conductors are promising materials for electrochemical hydrogen
sensors, which have already been used in commercialized hydrogen sensors for aluminum …
sensors, which have already been used in commercialized hydrogen sensors for aluminum …
Transport properties of B-site codoped CaHfO 3 proton conductors with octahedral distortion
W Huang, M Lv, Y Li, Y Ding, J Lu, C Zhuang, P Yue… - RSC …, 2024 - pubs.rsc.org
Perovskite-type solid electrolytes exhibit a diverse range of conductive properties due to the
competition and coupling of multiple degrees of freedom. In perovskite structures, B-site and …
competition and coupling of multiple degrees of freedom. In perovskite structures, B-site and …
Oxygen isotope exchange in doped calcium and barium zirconates
AS Farlenkov, MV Ananyev, VA Eremin… - Solid State Ionics, 2016 - Elsevier
The oxygen tracer diffusion coefficient and the oxygen surface exchange coefficient were
measured in CaZr 1− x Sc x O 3− x/2 (x= 0, 0.01, 0.05) and BaZr 0.8 Y 0.2 O 2.9 zirconates …
measured in CaZr 1− x Sc x O 3− x/2 (x= 0, 0.01, 0.05) and BaZr 0.8 Y 0.2 O 2.9 zirconates …