Dinuclear metal synergistic catalysis for energy conversion

DC Zhong, YN Gong, C Zhang, TB Lu - Chemical Society Reviews, 2023 - pubs.rsc.org
Catalysts featuring dinuclear metal sites are regarded as superior systems compared with
their counterparts with mononuclear metal sites. The dinuclear metal sites in catalysts with …

Molecular electrocatalysts for the oxygen reduction reaction

S Dey, B Mondal, S Chatterjee, A Rana… - Nature Reviews …, 2017 - nature.com
The past decade has seen considerable growth in the development of materials for fuel cell
electrodes, and there is a desire for active electrocatalysts derived from base metals instead …

Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes

AC Ghosh, C Duboc, M Gennari - Coordination Chemistry Reviews, 2021 - Elsevier
Transition metal-driven small molecule activation is essential for the production of fuels and
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …

Low overpotential water oxidation at neutral pH catalyzed by a copper (II) porphyrin

Y Liu, Y Han, Z Zhang, W Zhang, W Lai, Y Wang… - Chemical …, 2019 - pubs.rsc.org
Low overpotential water oxidation under mild conditions is required for new energy
conversion technologies with potential application prospects. Extensive studies on …

Structure effects of metal corroles on energy-related small molecule activation reactions

H Lei, X Li, J Meng, H Zheng, W Zhang, R Cao - ACS Catalysis, 2019 - ACS Publications
The increasing global energy and environmental crises make it urgent to find and use
renewable, clean, and environmentally benign new energy resources. New energy …

Bioinspired N4-metallomacrocycles for electrocatalytic oxygen reduction reaction

Y Li, N Wang, H Lei, X Li, H Zheng, H Wang… - Coordination Chemistry …, 2021 - Elsevier
Oxygen reduction reaction (ORR) is an important process involved in natural and artificial
energy conversion schemes. As inspired by cytochrome c oxidases (CcOs), which are …

Role of transition metals in catalyst designs for oxygen evolution reaction: A comprehensive review

Y Feng, H Yang, X Wang, C Hu, H Jing… - International Journal of …, 2022 - Elsevier
With the increasing demand for sustainable energy, human beings put forward higher
requirements for the preparation of clean energy. Electrocatalytic water splitting has become …

Supramolecular tuning enables selective oxygen reduction catalyzed by cobalt porphyrins for direct electrosynthesis of hydrogen peroxide

PT Smith, Y Kim, BP Benke, K Kim… - Angewandte …, 2020 - Wiley Online Library
We report a supramolecular strategy for promoting the selective reduction of O2 for direct
electrosynthesis of H2O2. We utilized cobalt tetraphenylporphyrin (Co‐TPP), an oxygen …

Structural tuning of heterogeneous molecular catalysts for electrochemical energy conversion

J Wang, S Dou, X Wang - Science Advances, 2021 - science.org
Heterogeneous molecular catalysts based on transition metal complexes have received
increasing attention for their potential application in electrochemical energy conversion. The …

Advances in the molecular catalysis of dioxygen reduction

CW Machan - ACS Catalysis, 2020 - ACS Publications
The reduction of dioxygen (O2) is of vital importance to energy-related reactions. In biology,
respiration uses O2 reduction as a thermodynamic sink, whereas fuel cells pair the oxygen …