Carbon dioxide hydrogenation over nickel-, ruthenium-, and copper-based catalysts: Review of kinetics and mechanism

K Jalama - Catalysis Reviews, 2017 - Taylor & Francis
This study critically reviews the mechanism of CO2 hydrogenation over Ni, Ru, and Cu, and
the effect of catalyst properties and operating conditions on reaction kinetics. Most studies …

CO2 Activation over Catalytic Surfaces

A Álvarez, M Borges, JJ Corral‐Pérez… - …, 2017 - Wiley Online Library
This article describes the main strategies to activate and convert carbon dioxide (CO2) into
valuable chemicals over catalytic surfaces. Coherent elements such as common …

Surface chemistry of carbon dioxide

HJ Freund, MW Roberts - Surface Science Reports, 1996 - Elsevier
The review discusses how CO2 surface chemistry has developed since the early 1950s.
Emphasis is given to studies of well-characterized surfaces of metals, oxides and some …

CO2 hydrogenation on Au/TiC, Cu/TiC, and Ni/TiC catalysts: Production of CO, methanol, and methane

JA Rodriguez, J Evans, L Feria, AB Vidal, P Liu… - Journal of catalysis, 2013 - Elsevier
Abstract Small Au, Cu, and Ni particles in contact with TiC (0 0 1) display a very high activity
for the catalytic hydrogenation of CO 2. The major product over these catalysts is CO which …

Recycling of CO2: Probing the Chemical State of the Ni(111) Surface during the Methanation Reaction with Ambient-Pressure X-Ray Photoelectron Spectroscopy

C Heine, BAJ Lechner, H Bluhm… - Journal of the American …, 2016 - ACS Publications
Using ambient-pressure X-ray photoelectron spectroscopy (AP-XPS), we studied the
adsorption and reactions of CO2 and CO2+ H2 on the Ni (111) surface to identify the surface …

DFT study of the water–gas shift reaction and coke formation on Ni (111) and Ni (211) surfaces

RC Catapan, AAM Oliveira, Y Chen… - The Journal of Physical …, 2012 - ACS Publications
We report for the first time results of a systematic density functional theory (DFT) study of the
water-gas shift (WGS) reaction and coke formation pathways on Ni (111) and Ni (211) …

Heterogeneous catalytic reactions of carbon dioxide

OV Krylov, AK Mamedov - Russian Chemical Reviews, 1995 - iopscience.iop.org
The most important classes of heterogeneous catalytic reactions involving CO 2 are
examined: the incorporation of CO 2 in the C–C, C–H, and C–N bonds with formation of …

Continuous CO2 capture and reduction in one process: CO2 methanation over unpromoted and promoted Ni/ZrO2

L Hu, A Urakawa - Journal of CO2 Utilization, 2018 - Elsevier
The recently demonstrated concept to combine CO 2 capture and utilization in one process
using isothermal unsteady-state operation, namely CO 2 capture and reduction (CCR), was …

Carbon dioxide hydrogenation on Ni (110)

E Vesselli, L De Rogatis, X Ding, A Baraldi… - Journal of the …, 2008 - ACS Publications
We demonstrate that the key step for the reaction of CO2 with hydrogen on Ni (110) is a
change of the activated molecule coordination to the metal surface. At 90 K, CO2 is …

CO2 chemisorption and dissociation on flat and stepped transition metal surfaces

W Jin, Y Wang, T Liu, C Ding, H Guo - Applied Surface Science, 2022 - Elsevier
As a promising and practical way to decrease CO 2 emissions, the conversion of CO 2 to
value-added chemicals has received significant recent attention. The activation of CO 2 on …