Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Enantioselective radical reactions using chiral catalysts

S Mondal, F Dumur, D Gigmes, MP Sibi… - Chemical …, 2022 - ACS Publications
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Transition metal catalysis controlled by hydrogen bonding in the second coordination sphere

JNH Reek, B de Bruin, S Pullen, TJ Mooibroek… - Chemical …, 2022 - ACS Publications
Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Thermal stability and explosive hazard assessment of diazo compounds and diazo transfer reagents

SP Green, KM Wheelhouse, AD Payne… - … process research & …, 2019 - ACS Publications
Despite their wide use in academia as metal-carbene precursors, diazo compounds are
often avoided in industry owing to concerns over their instability, exothermic decomposition …

Recent developments in enantioselective transition metal catalysis featuring attractive noncovalent interactions between ligand and substrate

A Fanourakis, PJ Docherty, P Chuentragool… - ACS …, 2020 - ACS Publications
Enantioselective transition metal catalysis is an area very much at the forefront of
contemporary synthetic research. The development of processes that enable the efficient …

Carbene radicals in transition-metal-catalyzed reactions

RFJ Epping, D Vesseur, M Zhou, B de Bruin - ACS catalysis, 2023 - ACS Publications
Discovered as organometallic curiosities in the 1970s, carbene radicals have become a
staple in modern-day homogeneous catalysis. Carbene radicals exhibit nucleophilic radical …

Cycloaddition reactions of enoldiazo compounds

QQ Cheng, Y Deng, M Lankelma… - Chemical Society Reviews, 2017 - pubs.rsc.org
Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …

Use of magnetic fields and nanoparticles to trigger drug release and improve tumor targeting

JF Liu, B Jang, D Issadore… - Wiley Interdisciplinary …, 2019 - Wiley Online Library
Drug delivery strategies aim to maximize a drug's therapeutic index by increasing the
concentration of drug at target sites while minimizing delivery to off‐target tissues. Because …

Organocobalt complexes as sources of carbon-centered radicals for organic and polymer chemistries

J Demarteau, A Debuigne, C Detrembleur - Chemical reviews, 2019 - ACS Publications
Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …