Mechanochemical tools for polymer materials

Y Chen, G Mellot, D van Luijk, C Creton… - Chemical Society …, 2021 - pubs.rsc.org
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …

Luminescent radicals

A Mizuno, R Matsuoka, T Mibu, T Kusamoto - Chemical Reviews, 2024 - ACS Publications
Organic radicals are attracting increasing interest as a new class of molecular emitters. They
demonstrate electronic excitation and relaxation dynamics based on their doublet or higher …

Thermo‐and mechanochromic camouflage and self‐healing in biomimetic soft actuators based on liquid crystal elastomers

Z Liu, HK Bisoyi, Y Huang, M Wang… - Angewandte Chemie …, 2022 - Wiley Online Library
In nature, many mysterious creatures capable of deformation camouflage, color camouflage,
and self‐healing have inspired scientists to develop various biomimetic soft robots …

A general organocatalytic system for electron donor–acceptor complex photoactivation and its use in radical processes

E de Pedro Beato, D Spinnato, W Zhou… - Journal of the …, 2021 - ACS Publications
We report herein a modular class of organic catalysts that, acting as donors, can readily form
photoactive electron donor–acceptor (EDA) complexes with a variety of radical precursors …

An overview of dynamic covalent bonds in polymer material and their applications

S Huang, X Kong, Y Xiong, X Zhang, H Chen… - European Polymer …, 2020 - Elsevier
Dynamic covalent bonds (DCBs) have received widespread attention due to their unique
reversibility and stimulus responsiveness. The introduction of DCBs often endows materials …

Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities

ZP Zhang, MZ Rong, MQ Zhang - Progress in Polymer Science, 2018 - Elsevier
Reversible covalent polymers are able to change their bond arrangement and structure via
reversible reaction triggered by external stimuli including heating, light and pH, while …

Advances in injectable self-healing biomedical hydrogels

Y Tu, N Chen, C Li, H Liu, R Zhu, S Chen, Q Xiao, J Liu… - Acta Biomaterialia, 2019 - Elsevier
In recent years, implantable biomaterials have attracted significant interest owing to their
potentials for use in the therapy of physical defects and traumas. Among the implantable …

Self-healing gels based on constitutional dynamic chemistry and their potential applications

Z Wei, JH Yang, J Zhou, F Xu, M Zrínyi… - Chemical Society …, 2014 - pubs.rsc.org
As representative soft materials with widespread applications, gels with various functions
have been developed. However, traditional gels are vulnerable to stress-induced formation …

Advances in radical-trapping antioxidant chemistry in the 21st century: a kinetics and mechanisms perspective

KU Ingold, DA Pratt - Chemical reviews, 2014 - ACS Publications
Under normal atmospheric partial pressure of oxygen, the rate of reaction 3 is much lower
than the rate of reaction 2; therefore, the steady-state concentration of ROO• is very much …

[图书][B] Comprehensive handbook of chemical bond energies

YR Luo - 2007 - taylorfrancis.com
Understanding the energy it takes to build or break chemical bonds is essential for scientists
and engineers in a wide range of innovative fields, including catalysis, nanomaterials …