Carbon or silicon radicals with silyl substituents are important intermediates in
organometallic and organic chemistry.[1] Already in 1970, Bassindale et al. had reported the …

A halogen-substituted cyclic disilene compound, bromocyclotrisilene, Si3Br (Eind) 3 (3a),
bearing fused-ring bulky Eind (a: R1= R2= Et) groups, has been synthesized as an …

The chemistry of oligosilanes has made numerous advances since the beginning of the new
millennium. While during the time from the 1960s to the 1990s research has concentrated on …

In the present chapter, the recent progress in the chemistry of disilenes (R 2 Si= SiR 2) with
functional groups in the last decade will be reviewed. Especially, novel synthetic routes to …

The development of electrical energy storage devices that can operate at high charge and
discharge rates is fundamentally important, however although electrochemical capacitors …

The synthesis of persistent sila‐and germacyclopentadienyl (silolyl‐and germolyl‐) radicals
by careful stoichiometric reduction of the corresponding halides with potassium is reported …

High-frequency and-field electron paramagnetic resonance (HFEPR), in its current
configuration (frequencies up to 1THz; fields up to 35T), has been applied to transition metal …

Due to its unique properties, elemental silicon is a pivotal material in modern society. Even
though a few other semiconductors, eg, gallium arsenide, rival silicon in some performance …

Abstract Reductive deiodination of 1, 3, 5-tris [2, 2-di-tert-butyl-1-(di-tert-butylmethylsilyl)-1-
iodo-2-methyldisilanyl] benzene (1) with KC8 results in the formation of isolable Si-centered …

Isolable aryl‐substituted silyl radicals (tBu2MeSi) 2 (Ar) Si.(Ar= C6H5, 4‐tBuC6H4, 4‐
PhC6H4, 3, 5‐tBu2C6H3) were synthesized by the reaction of the corresponding iodosilane …