Structure sensitivity and nanoscale effects in electrocatalysis

MTM Koper - Nanoscale, 2011 - pubs.rsc.org
This review discusses the role of the detailed nanoscale structure of catalytic surfaces on the
activity of various electrocatalytic reactions of importance for fuel cells, hydrogen production …

Single entity electrocatalysis

TB Clarke, LE Krushinski, KJ Vannoy… - Chemical …, 2024 - ACS Publications
Making a measurement over millions of nanoparticles or exposed crystal facets seldom
reports on reactivity of a single nanoparticle or facet, which may depart drastically from …

How palladium inhibits CO poisoning during electrocatalytic formic acid oxidation and carbon dioxide reduction

X Chen, LP Granda-Marulanda, IT McCrum… - Nature …, 2022 - nature.com
Abstract Development of reversible and stable catalysts for the electrochemical reduction of
CO2 is of great interest. Here, we elucidate the atomistic details of how a palladium …

High-Throughput Computational Screening of Bioinspired Dual-Atom Alloys for CO2 Activation

D Behrendt, S Banerjee, C Clark… - Journal of the American …, 2023 - ACS Publications
CO2 activation is an integral component of thermocatalytic and electrocatalytic CO2
conversion to liquid fuels and value-added chemicals. However, the thermodynamic stability …

Enhanced Formic Acid Oxidation over SnO2-decorated Pd Nanocubes

C Rettenmaier, RM Arán-Ais, J Timoshenko… - ACS …, 2020 - ACS Publications
The formic acid oxidation reaction (FAOR) is one of the key reactions that can be used at the
anode of low-temperature liquid fuel cells. To allow the knowledge-driven development of …

The catalytic mechanics of dynamic surfaces: stimulating methods for promoting catalytic resonance

M Shetty, A Walton, SR Gathmann, MA Ardagh… - ACS …, 2020 - ACS Publications
Transformational catalytic performance in rate and selectivity is obtainable through catalysts
that change on the time scale of catalytic turnover frequency. In this work, dynamic catalysts …

[图书][B] Electroanalytical Chemistry: A Series of Advances: Volume 23

AJ Bard, CG Zoski - 2010 - taylorfrancis.com
Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

Mechanism of the electrocatalytic oxidation of formic acid on metals

A Cuesta, G Cabello, M Osawa, C Gutiérrez - Acs Catalysis, 2012 - ACS Publications
We present a detailed spectrokinetic study of the electrocatalytic oxidation of formic acid on
Au and Pt electrodes using ATR-SEIRAS that has allowed us to unveil the mechanisms of …

[PDF][PDF] The role of bridge‐bonded adsorbed formate in the electrocatalytic oxidation of formic acid on platinum

M Osawa, K Komatsu, G Samjeské, T Uchida… - Angewandte …, 2011 - academia.edu
The oxidation of formic acid (HCOOH) on platinum electrodes has been extensively
investigated as a model electrocatalytic reaction.[1–4] It is generally accepted that HCOOH …

Tailoring Au-core Pd-shell Pt-cluster nanoparticles for enhanced electrocatalytic activity

PP Fang, S Duan, XD Lin, JR Anema, JF Li… - Chemical …, 2011 - pubs.rsc.org
We have rationally synthesized and optimized catalytic nanoparticles consisting of a gold
core, covered by a palladium shell, onto which platinum clusters are deposited (Au@ Pd …