Electrolytes are central to life and technology but lack complete understanding. Recent experiments with highly concentrated electrolytes have revealed electrostatic decay lengths …
J Huang, S Chen, M Eikerling - Journal of chemical theory and …, 2021 - ACS Publications
A hybrid density–potential functional of an electrochemical interface that encompasses major effects in the contacting metal and electrolyte phases is formulated. Variational …
ZAH Goodwin, AA Kornyshev - Electrochimica Acta, 2022 - Elsevier
Here we investigate a limiting case of the theory for aggregation and gelation in the electrical double layer (EDL) of ionic liquids (ILs). The limiting case investigated only …
P Cats, R van Roij - The Journal of Chemical Physics, 2021 - pubs.aip.org
In this work, we theoretically study the differential capacitance of an aqueous electrolyte in contact with a planar electrode, using classical density functional theory, and show how this …
L Qing, J Jiang - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
The advanced supercapacitor is of great significance for renewable energy storage. Achieving its high energy and high power densities remains a huge challenge. Herein, the …
BB Ye, ZG Wang - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
Recent mean-field theories predict that room-temperature ionic liquid (RTIL) electric double- layer capacitors (EDLCs) undergo a spontaneous surface charge separation (SSCS) with no …
In the present investigation, we have synthesized samarium (Sm) nanoparticles (NPs) and anchored them onto the surface of CuO: CoO nanostructure (NS) by utilizing a simple …
S Zhou - The Journal of Chemical Physics, 2019 - pubs.aip.org
By using classical density functional theory, we study the effects of interionic nonhard sphere neutral interaction (NHSNI) and solvent crowding on curve of differential electrical …
We use a mean field model for ionic liquids, which takes into account both the ion correlation and the finite ion size effects, in order to calculate the differential capacitance of the ionic …