In the last two decades, a number of synthetic iron-based biomimetic catalyst systems for the
selective oxidation of organic compounds, such as epoxidations of alkenes and C–H …

Heterogeneous catalysis in water has not been explored beyond certain advantages such
as recyclability and recovery of the catalysts from the reaction medium. Moreover, poor yield …

Deprotonated carboxamidate 'N'donors have been extensively explored as ligands to
support metal ions with unusual higher oxidation states. Their ability to serve as both σ and …

Cytochrome P450, one of nature's oxidative workhorses, catalyzes the oxidation of C–H
bonds in complex biological settings. Extensive research has been conducted over the past …

An efficient electrochemical method for the selective oxidation of C–H bonds of unactivated
alkanes (BDE≤ 97 kcal mol− 1) and CC bonds of alkenes using a biomimetic iron …

Acid effects on the chemical properties of metal–oxygen intermediates have attracted much
attention recently, such as the enhanced reactivity of high-valent metal (IV)–oxo species by …

The selective oxidation of alkane and olefin moieties are reactions of fundamental
importance in both chemical synthesis and biology. Nature efficiently catalyzes the oxidation …

Oxidations of C–H bonds with m-chloroperoxybenzoic acid (m-CPBA) catalyzed by transition
metal complexes are known to proceed through a number of routes, from the non-selective …

High-valent iron–oxo species (Fe Ⅳ/Ⅴ= O), generated via peroxide activation with Fe-based
catalysts, have shown potential in the selective and efficient degradation of organic …

The effect of HClO4 on the reactivity and selectivity of the catalyst systems 1, 2/H2O2/AcOH,
based on nonheme iron complexes of the PDP families,[(Me2OMePDP) FeIII (μ-OH) 2FeIII …