Manganese at work: carbonyl bipyridyl complexes based on manganese, a non-noble
abundant and inexpensive metal, have been proved to be excellent molecular catalysts for …

It is about 20 years since the combination of transition-metal catalysis and electroreduction
was shown to be applicable to the coupling of organic molecules. This was followed by a …

Synthetically useful radical thiol–ene reactions can be initiated by visible light irradiation in
the presence of transition metal polypyridyl photocatalysts. The success of this method relies …

Lithium-mediated electrochemical reduction of N 2 to NH 3 was achieved. NH 3 was formed
with significant current efficiency (up to 8%) by the electrolysis of a solution of LiClO 4 (0.2 …

Despite advances in the development of molecular catalysts capable of reducing dinitrogen
to ammonia using proton donors and chemical reductants, few molecular electrocatalysts …

A novel electrochemical N 2 reduction system is reported. Ammonia was formed with a
significant current efficiency (up to 8%) by a simple electrolysis, which was conducted under …

Conclusion In summary, on the basis of angle-resolved photoemission results and MNDO
theoretical calculations, it appears that the initial adsorption of diethylcarborane on Si (111) …

We report coupling reactions of organic derivatives through catalysis by nickel and
palladium complexes combined with electrochemical methods. Arylation, carboxylation …

The electrochemical fixation of carbon dioxide (CO2) into organic halides is one of the most
prominent strategies for mitigating atmospheric CO2 emission, along with the difficulties …

Manganese carbonyl complexes have been studied extensively in solution as low cost,
selective electrocatalysts with a low overpotential for CO2 reduction but experiments are …