Importance of size and contact structure of gold nanoparticles for the genesis of unique catalytic processes

T Ishida, T Murayama, A Taketoshi, M Haruta - Chemical reviews, 2019 - ACS Publications
Since the discovery of catalysis by Au nanoparticles (NPs), unique catalytic features of Au
have appeared that are greatly different from those of Pd and Pt. In this Review, we aimed to …

How catalysts and experimental conditions determine the selective hydroconversion of furfural and 5-hydroxymethylfurfural

S Chen, R Wojcieszak, F Dumeignil, E Marceau… - Chemical …, 2018 - ACS Publications
Furfural and 5-hydroxymethylfurfural stand out as bridges connecting biomass raw materials
to the biorefinery industry. Their reductive transformations by hydroconversion are key …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …

Role of the support in gold-containing nanoparticles as heterogeneous catalysts

M Sankar, Q He, RV Engel, MA Sainna… - Chemical …, 2020 - ACS Publications
In this review, we discuss selected examples from recent literature on the role of the support
on directing the nanostructures of Au-based monometallic and bimetallic nanoparticles. The …

Surface-plasmon-driven hot electron photochemistry

Y Zhang, S He, W Guo, Y Hu, J Huang… - Chemical …, 2017 - ACS Publications
Visible-light-driven photochemistry has continued to attract heightened interest due to its
capacity to efficiently harvest solar energy and its potential to solve the global energy crisis …

Advances in materials and applications of inorganic electrides

H Hosono, M Kitano - Chemical Reviews, 2021 - ACS Publications
Electrides are materials in which electrons serve as anions. Here, the concept of inorganic
electrides is extended in several respects: from ionic crystals to intermetallic compounds in …

Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H2 on Au

S Mukherjee, F Libisch, N Large, O Neumann… - Nano …, 2013 - ACS Publications
Heterogeneous catalysis is of paramount importance in chemistry and energy applications.
Catalysts that couple light energy into chemical reactions in a directed, orbital-specific …

State of the art in gold nanoparticle synthesis

P Zhao, N Li, D Astruc - Coordination Chemistry Reviews, 2013 - Elsevier
General principles and recent developments in the synthesis of gold nanoparticles (AuNPs)
are reviewed. The “in situ” Turkevich-Frens and Brust-Schiffrin methods are still major …

A review of state of the art in phosphine ligated gold clusters and application in catalysis

RH Adnan, JML Madridejos, AS Alotabi… - Advanced …, 2022 - Wiley Online Library
Atomically precise gold clusters are highly desirable due to their well‐defined structure
which allows the study of structure–property relationships. In addition, they have potential in …