The electronic structure of biradicals is characterized by the presence of two unpaired
electrons in degenerate or near‐degenerate molecular orbitals. In particular, some of the …

Carbonyl nitrenes are versatile intermediates that have been extensively characterized;
however, their phosphorus analogues remain largely unknown. Herein, we report the …

Phosphinidenes are heavy congeners of nitrenes that have been broadly used as in situ
reagents in synthetic phosphorus chemistry and also serve as versatile ligands in …

Phosphenic isocyanate (O2PNCO), a novel phosphorus-containing small molecule has
been generated by thermolysis of a dioxaphospholane-based precursor. The …

Singlet fission (SF) is considered as a promising strategy to overcome the Shockley–
Queisser limit of single-junction solar cells. However, only a handful of chromophores were …

Methyl and methylene compounds of arsenic and antimony have been studied by
photoelectron photoion coincidence spectroscopy to investigate their relative stability. While …

Understanding how isomerism influences photoelectron spectra helps in the assignment
and analysis of reactive mixtures, especially for heterocycles with numerous isomers …

This dissertation aimed to understand and model the pyrolysis and oxidation mechanisms of
carbonate and phosphate esters. With the increasing demand for lithium-ion batteries (LIBs) …