Tuning Phosphine Oxide-Substituted ortho-Carboranes for Improved Biphasic Electrochemical UO22+ Capture and Release

S Heinrich, H Benhaim, M Mattejat, D Pan… - Inorganic …, 2023 - ACS Publications
We report the synthesis and characterization of a series of new, tunable 1, 2-bis
(diarylphosphine oxide)-ortho-carboranes, derivatives of our previously reported uranyl …

Lewis base adducts of NpCl 4

LM Lopez, MC Uible, M Zeller, SC Bart - Chemical Communications, 2024 - pubs.rsc.org
Np (IV) Lewis base adducts were prepared by ligand substitution of NpCl4 (DME) 2. Using
acetonitrile and pyridine, NpCl4 (MeCN) 4 (1) and NpCl4 (pyr) 4 (2) were isolated …

Synthesis and fluorescence spectroscopy of tris (pyrenyl) pnictogen compounds

K Behm, JB Essner, CL Barnes, GA Baker… - Dalton …, 2017 - pubs.rsc.org
The synthesis, characterization, and fluorescence spectroscopy of E (C16H9) 3 complexes
(E= P, As, Sb, and Bi), as well as OP (C16H9) 3, OAs (C16H9) 3, and SP (C16H9) 3, is …

Synthesis, spectroscopy, electrochemistry, and coordination chemistry of substituted phosphine sulfides and selenides

AT Breshears, AC Behrle, CL Barnes, CH Laber… - Polyhedron, 2015 - Elsevier
Phosphines and phosphine chalcogenides are important ligands for various metal systems,
especially catalysts. Based on previously synthesized phosphine oxide ligands, we describe …

Synthesis of hexavalent molybdenum formo-and aceto-hydroxamates and deferoxamine via liquid-liquid metal partitioning

AT Breshears, MA Brown, I Bloom, CL Barnes… - Inorganica Chimica …, 2018 - Elsevier
We report a new method of crystal growth and synthesis based on liquid-liquid partitioning
that allows for isolation and in-depth characterization of molybdenyl bis (formohydroxamate) …