What are the reaction mechanisms responsible for the selective product formation in
catalysis? How can we identify the reactive intermediates steering the reaction towards the …

Photoelectron spectroscopy has long been a powerful method in the toolbox of experimental
physical chemistry and molecular physics. Recent improvements in coincidence methods …

Quantitative speciation data for alternative fuels is highly desired to assess their emission
potential and to develop and validate chemical kinetic models. In terms of substitute choices …

The electronic structure of biradicals is characterized by the presence of two unpaired
electrons in degenerate or near‐degenerate molecular orbitals. In particular, some of the …

Determination of high-dimensional potential energy surfaces (PESs) and nonadiabatic
couplings have always been quite challenging. To this end, machine learning (ML) models …

The vacuum ultraviolet photoionization of the methyl peroxy radical, CH 3 O 2, and
unimolecular dissociation of internal energy selected CH 3 O 2+ cations were investigated in …

To address current challenges related to climate change, novel concepts, such as engine-
based polygeneration under fuel-rich conditions, have recently been developed. In this …

We present here a synchrotron radiation vacuum ultraviolet photoionization study of the
simplest alkoxy radical, CH 3 O, a key reaction intermediate in atmospheric and combustion …

Shock tube techniques for kinetic studies are continuously evolving driven by advances in
kinetic modeling and detection techniques. An innovative category of shock tubes has been …

Mass selected slow photoelectron spectra (SPES) of three boron-containing reactive
species, BH2, BH, and BF were recorded by double imaging photoion–photoelectron …