Conspectus Low-valent, low-coordinate 3d metal complexes represent a class of
extraordinarily reactive compounds that can act as reagents and catalysts for challenging …

Conspectus Nickel pincer systems have recently attracted much attention for applications in
various organometallic reactions and catalysis involving small molecule activation. Their …

Nickel PyBox catalysts promote nucleophilic cyclopropanation reactions using CH2Cl2 as a
methylene source and Mn as a stoichiometric reductant. The substrate scope includes a …

Large-scale CO2 hydrogenation could offer a renewable stream of industrially important C1
chemicals while reducing CO2 emissions. Critical to this opportunity is the requirement for …

Bi-Oxazoline (biOx) has emerged as an effective ligand framework for promoting nickel-
catalyzed cross-coupling, cross-electrophile coupling, and photoredox-nickel dual catalytic …

One-electron oxidation of palladium (0) and platinum (0) bis (phosphine) complexes
enables isolation of a homologous series of linear d9 metalloradicals of the form [M (PR3) …

Herein, we report the efficient degradation of N2O with a well‐defined bis (silylene) amido
iron complex as catalyst. The deoxygenation of N2O using the iron silanone complex 4 as a …

A mononuclear, T‐shaped palladium (I) d9 metalloradical (3), stabilized by a bulky
carbazole‐based PNP‐ligand, was obtained by reduction of palladium chloride or thermal …

Incorporation of two 9-borabicyclo [3.3. 1] nonyl substituents within the secondary
coordination sphere of a pincer-based Fe (II) complex provides Lewis acidic sites capable of …

Enforcing unusually low coordination numbers on transition metals with sterically
demanding ligands has long been an area of interest for chemists. Historically, the synthesis …