After conquering the atomic structure about a century ago, chemists have been largely
interested in understanding the concept of chemical bond and the formation of a molecule …

In the last decade, experiment and theory have expanded our vision of non‐covalent
interactions (NCIs), shifting the focus from the conventional hydrogen bond to new bridging …

The development of high-fidelity mechanisms for chemically reactive systems is a
challenging process that requires the compilation of rate descriptions for a large and …

Broadband chirped-pulse Fourier transform microwave (CP-FTMW) spectrometers have
increased the sensitivity for molecular rotational spectroscopy. The measurement dynamic …

The covalent diamantyl (C28H38) and oxadiamantyl (C26H34O2) dimers are stabilized by
London dispersion attractions between the dimer moieties. Their solid-state and gas-phase …

We used jet-cooled broadband rotational spectroscopy to explore the balance between π-
stacking and hydrogen-bonding interactions in the self-aggregation of thiophenol. Two …

π-Stacking is a common descriptor for face-to-face attractive forces between aromatic
hydrocarbons. However, the physical origin of this interaction remains debatable. Here we …

Recent studies demonstrate that simple functional molecules, which usually form two-
dimensional (2D) crystal structures when adsorbed on solid substrates, are also able to self …

Rotational spectra of the three most stable conformers (I, II, III) of the ternary 2, 2, 2‐
trifluoroethanol (TFE) cluster were measured using Fourier transform microwave …

Recent advances in the application of molecular rotational spectroscopy to chiral analysis
are described. These include the use of broadband rotational spectroscopy for the analysis …