Transition-metal mediated carbon–sulfur bond activation and transformations: an update

J Lou, Q Wang, P Wu, H Wang, YG Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

Intramolecular Desulfitative Coupling: Nickel-Catalyzed Transformation of Diaryl Sulfones into Biaryls via Extrusion of SO2

F Takahashi, K Nogi, H Yorimitsu - Organic letters, 2018 - ACS Publications
As a new transformation of organosulfur compounds, intramolecular desulfitative coupling of
diaryl sulfones to the corresponding biaryls has been developed with the aid of nickel–NHC …

Pd-catalyzed tandem reaction of 2-aminostyryl nitriles with arylboronic acids: synthesis of 2-arylquinolines

T Xu, Y Shao, L Dai, S Yu, T Cheng… - The Journal of Organic …, 2019 - ACS Publications
A novel palladium-catalyzed protocol for the synthesis of 2-arylquinolines via tandem
reaction of 2-aminostyryl nitriles with arylboronic acids has been developed with good …

Palladium-Catalysed Intermolecular Direct C–H Bond Arylation of Heteroarenes with Reagents Alternative to Aryl Halides: Current State of the Art

R Rossi, M Ciofalo - Current Organic Chemistry, 2022 - ingentaconnect.com
This unprecedented review with 322 references provides a critical up-to-date picture of the
Pd-catalysed intermolecular direct C–H bond arylation of heteroarenes with arylating …

Ruthenium (II)-Catalyzed Chelation-Assisted Desulfitative Arylation of Benzo [h] quinolines with Arylsulfonyl Chlorides

YX Xu, YQ Liang, ZJ Cai, SJ Ji - Organic Letters, 2022 - ACS Publications
Herein, a novel chelation-assisted C–H arylation reaction of benzo [h] quinoline is
described. This transformation, using [RuCl2 (p-cymene)] 2 as the catalyst and cheap and …

A radical Smiles rearrangement difunctionalization of activated alkenes via desulfonylation and insertion of sulfur dioxide relay strategy

SW Tian, ZT Luo, BQ Xiong, KW Tang, PF Huang… - Green …, 2024 - pubs.rsc.org
A visible-light-induced difunctionalization of activated alkenes for building alkylsulfonylated
oxindoles and amides through a radical Smiles rearrangement strategy was reported. A …

PPh3‐Mediated Nucleophilic Sulfonation of Sulfonyl Chlorides with Arynes: Access to Manifold Aryl Sulfones

HQ Yue, QW Li, DW Shi, RJ Yang… - European Journal of …, 2023 - Wiley Online Library
Sulfonyl chlorides are a class of cheap and readily available basic chemicals, which have
routinely served as electrophilic reagents in their chemical transformations. Herein, we …

Palladium-catalyzed Successive C–H bond Arylations and Annulations toward the π-Extension of Selenophene-containing Aromatic Skeletons

X Shi, S Mao, T Roisnel, H Doucet… - Organic Chemistry …, 2019 - pubs.rsc.org
A modular approach for the synthesis of planar π-extended selenium containing molecules
from selenophene has been developed. Different combinations of Pd-catalyzed desulfitative …

Transition metal-free approaches to biaryls

F Piazzolla, F Colognese… - Current Organic …, 2018 - benthamdirect.com
Biaryls are a key structural motif in compounds with various applications, ranging from
pharmaceuticals to material science, including ligands for organic synthesis. Given the …

Pd(OAc)2/Xantphos Catalyzed Reductive Coupling of Sulfonyl Chlorides: Synthesis of Thioethers by Sulphur Dioxide Extrusion

G Zhang, ZM Sang, QH Wang, JA Chen… - ChemistrySelect, 2023 - Wiley Online Library
Herein, we reported a successful cross coupling of aryl sulfonyl chlorides to forge thioether
skeleton via Pd catalysis. This transformation proceeded in the presence of Xantphos …