Structural analysis of molecular materials using the pair distribution function

MW Terban, SJL Billinge - Chemical Reviews, 2021 - ACS Publications
This is a review of atomic pair distribution function (PDF) analysis as applied to the study of
molecular materials. The PDF method is a powerful approach to study short-and …

Understanding the opportunities of metal–organic frameworks (MOFs) for CO 2 capture and gas-phase CO 2 conversion processes: a comprehensive overview

J Gandara-Loe, L Pastor-Perez, LF Bobadilla… - Reaction Chemistry & …, 2021 - pubs.rsc.org
The rapid increase in the concentration of atmospheric carbon dioxide is one of the most
pressing problems facing our planet. This challenge has motivated the development of …

Enhanced CO2 methanation activity over Ni/CeO2 catalyst by one-pot method

R Tang, N Ullah, Y Hui, X Li, Z Li - Molecular Catalysis, 2021 - Elsevier
Carbon dioxide hydrogenation for value-added chemicals has been regarded as a
promising way for CO 2 utilization. This paper describes the preparation of Ni/CeO 2 …

Ni-based electrocatalysts for unconventional CO2 reduction reaction to formic acid

E Lepre, J Heske, M Nowakowski, E Scoppola, I Zizak… - Nano Energy, 2022 - Elsevier
Electrochemical reduction stands as an alternative to revalorize CO 2. Among the different
alternatives, Ni single atoms supported on carbonaceous materials are an appealing …

Mechanistic insights into nanoparticle formation from bimetallic metal–organic frameworks

Z Chen, Z Chen, OK Farha… - Journal of the American …, 2021 - ACS Publications
Understanding and controlling nanomaterial structure, chemistry, and defects represents a
synthetic and characterization challenge. Metal–organic frameworks (MOFs) have recently …

Deciphering the structure of heterogeneous catalysts across scales using pair distribution function analysis

NK Zimmerli, CR Müller, PM Abdala - Trends in Chemistry, 2022 - cell.com
Heterogeneous catalysts are complex materials, often containing multiple atomic species
and phases with various degrees of structural order. The identification of structure …

Quick and robust PDF data acquisition using a laboratory single-crystal X-ray diffractometer for study of polynuclear lanthanide complexes in solid form and in solution

D Tsymbarenko, D Grebenyuk… - Journal of Applied …, 2022 - journals.iucr.org
Self-assembled polynuclear lanthanide hydroxo complexes are important objects in the
reticular chemistry approach to the design of various functional materials. Revealing their …

Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation

S Weber, RT Zimmermann, J Bremer, KL Abel… - …, 2022 - Wiley Online Library
There is considerable motivation in the catalysis community and chemical industry to
envision a future where rational catalyst design and targeted chemical process optimization …

Cu Nanoclusters Anchored on the Metal–Organic Framework for the Hydrolysis of Ammonia Borane and the Reduction of Quinolines

R Yun, B Zhang, F Zhan, L Du, Z Wang… - Inorganic …, 2021 - ACS Publications
Free-access active sites created and the interaction regulated between them and substrates
during the heterogeneous catalysis process are crucial, which remain a great challenge. In …

Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal–organic framework using in situ total scattering

N Prinz, S Strübbe, M Bauer, M Zobel - New Journal of Chemistry, 2023 - pubs.rsc.org
For improved and rational design of catalysts, in-depth knowledge of their formation and
structural evolution during synthesis is a key parameter. Thus, the preparation of a Ni …