As members of the same group in the periodic table, the industrially significant elements
aluminum and gallium exhibit strong similarities in the majority of their compounds. In …

The chemistry of low valent aluminum and gallium compounds is a very topical area of
research. Accompanying the preparative challenge in synthesizing novel types of main …

New record size! The reaction of Li [N (SiMe3) 2] with a metastable solution of GaBr leads to
good yields of [Ga84 {N (SiMe3) 2} 20] 4−(see picture), the largest Group 13 metalloid …

Atom‐precise, ligand‐stabilized metalloid clusters have emerged as outstanding model
systems to study fundamental structure and bonding situations of compositionally related …

Abstract Die technisch wichtigen Elemente Aluminium und Gallium weisen als Nachbarn im
Periodensystem in den meisten ihrer Verbindungen starke Ähnlichkeiten auf. Dagegen gibt …

Subvalent compounds, that is, metal‐rich substances in which the average oxidation state of
the cation is smaller than would be expected from the (8− N) rule, have proved to be a rich …

In this article, we discuss the synthesis of tetrameric and monomeric aluminium (I)
compounds. These compounds are prepared by reduction of the respective Al–X (X= halide) …

Reduction of indium boryl precursors to give two‐and three‐dimensional M− M bonded
networks is influenced by the choice of supporting ligand. While the unprecedented …

The reaction of (AlI⊙ NEt3) 4 with donor-free t-Bu3SiNa in toluene at− 78° C leads to the
generation and crystallization of Al4 [Si (t-Bu) 3] 4, which after Al4Cp* 4 is the second …

Neuer Größenrekord! Die Reaktion von Li [N (SiMe3) 2] mit einer metastabilen GaBr‐
Lösung führt in guten Ausbeuten zu [Ga84 {N (SiMe3) 2} 20] 4−(siehe Bild), dem größten …