Enantiopure diarylmethanols, propargylic and allylic alcohols are important building blocks
for the synthesis of a plethora of natural products and pharmaceutically relevant compounds …

The goal of this review is to collect the major developments in enantioselective titanium-
promoted 1, 2-alkylation, 1, 2-arylation, 1, 2-alkynylation, 1, 2-allylation and 1, 2-vinylation …

The first synthesis of the biologically active humulene natural product asteriscunolide D has
been accomplished in nine steps without the use of protecting groups. The challenging 11 …

By controlling the kinetics of alkynylation over aldolisation (by slowing adding the acceptor),
the challenging asymmetric catalytic alkynylation of acetaldehyde has been realized. This …

The development of a general and practical zinc‐catalyzed enantioselective alkyne addition
methodology is reported. The commercially available ProPhenol ligand (1) has facilitated …

A series of Schiff base ligands were synthesized from (1R)-camphor. Under the optimal
conditions,(+)-SBAIB-a, 10 was found to be an excellent catalyst for the enantioselective …

An efficient and widely applicable preparation of γ-hydroxy-α, β-acetylenic esters is
described by means of a one-pot dehydrobromination of a 2-bromoacrylate ester with LTMP …

Carbohydrate‐based benzylidene acetals undergo reductive ring opening. 1‐β‐O‐Acyl
glucoside conjugates of phenylacetic acids have been synthesized, and their acyl migration …

This review collects the recent developments in the field of enantioselective titanium-
catalyzed transformations published since the beginning of 2015, illustrating the power of …

A general strategy toward the total synthesis of biologically important C17 polyacetylenes
family such as virols A and C has been developed, which employed the (R, R)-ProPhenol/Zn …