Separation and complexation of f-block elements using hard-soft donors combined phenanthroline extractants

L Xu, X Yang, A Zhang, C Xu, C Xiao - Coordination Chemistry Reviews, 2023 - Elsevier
The chemical separation of minor actinides (MAs) over lanthanides from high-level waste
(HLW) is one of the hottest and most difficult topics in international separation science. N, O …

Sulfur donating extractants for the separation of trivalent actinides and lanthanides

NP Bessen, JA Jackson, MP Jensen… - Coordination Chemistry …, 2020 - Elsevier
The effective separation of trivalent actinides and lanthanides is capable of reducing the
long term radiation hazard associated with used nuclear fuel. This class of separation …

Direct Selective Extraction of Actinides (III) from PUREX Raffinate using a Mixture of CyMe4BTBP and TODGA as 1-cycle SANEX Solvent Part III: Demonstration of a …

A Wilden, G Modolo, C Schreinemachers… - … Extraction and Ion …, 2013 - Taylor & Francis
The direct selective separation of the trivalent actinides americium and curium from a
simulated Plutonium Uranium Refining by EXtraction (PUREX) raffinate solution by a …

Critical fluctuations in liquid–liquid extraction organic phases controlled by extractant and diluent molecular structure

BL Bonnett, D Sheyfer, PN Wimalasiri… - Physical Chemistry …, 2023 - pubs.rsc.org
Extractant aggregation in liquid–liquid extraction organic phases impacts extraction
energetics and is related to the deleterious efficiency-limiting liquid–liquid phase transition …

Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand

J Su, T Cheisson, A McSkimming, CAP Goodwin… - Chemical …, 2021 - pubs.rsc.org
There is significant interest in ligands that can stabilize actinide ions in oxidation states that
can be exploited to chemically differentiate 5f and 4f elements. Applications range from …

Use of polyaminocarboxylic acids as hydrophilic masking agents for fission products in actinide partitioning processes

M Sypula, A Wilden, C Schreinemachers… - … Extraction and Ion …, 2012 - Taylor & Francis
During the partitioning of trivalent actinides from High Active Raffinate (HAR) solutions, most
processes have to cope with an undesirable co-extraction of some of the fission products …

Hexavalent Actinide Extraction Using N,N-Dialkyl Amides

K McCann, BJ Mincher, NC Schmitt… - Industrial & Engineering …, 2017 - ACS Publications
Recently, efforts toward closing the nuclear fuel cycle have considered oxidizing americium
to a hexavalent, linear-dioxo cation for co-recovery with hexavalent U, Np, and Pu from …

Review of on-line and near real-time spectroscopic monitoring of processes relevant to nuclear material management

P Tse, SA Bryan, NP Bessen, AM Lines, JC Shafer - Analytica chimica acta, 2020 - Elsevier
Spectroscopic chemometric based on-line monitoring of used nuclear fuel (UNF)
reprocessing solutions and characterization of legacy nuclear waste (LNW) stored at …

Complexation of lanthanides and heavy actinides with aqueous sulfur-donating ligands

NP Bessen, IA Popov, CR Heathman… - Inorganic …, 2021 - ACS Publications
The separation of trivalent lanthanides and actinides is challenging because of their similar
sizes and charge densities. S-donating extractants have shown significant selectivity for …

Hexavalent americium recovery using copper (III) periodate

K McCann, DM Brigham, S Morrison… - Inorganic …, 2016 - ACS Publications
Separation of americium from the lanthanides is considered one of the most difficult
separation steps in closing the nuclear fuel cycle. One approach to this separation could …