[HTML][HTML] Research progress on design, synthesis and performance of energetic polynitro hexaazaisowurtzitane derivatives: Towards improved CL-20 analogues

VV Parakhin, GA Smirnov - FirePhysChem, 2024 - Elsevier
In order to discover of high-energy materials with characteristics that surpass modern
benchmarks, it is necessary to study the widest range of potential structures. The design of …

1, 3-Bishomocubane: a kinetic rock, a thermodynamic powerhouse and a compelling chiral synthetic scaffold

GL Tejashree, A Dave, N Kumbhakarna… - Chemical …, 2024 - pubs.rsc.org
Over the last several decades, saturated polycyclic cage compounds have remained a point
of interest for organic chemists because of their unique characteristics and reactivity. For the …

Molecular Acrobatics in Polycyclic Frames: Synthesis of “Kurmanediol” via Post-synthetic Modification of Cage Molecules by Olefinic Metathesis

S Kotha, G Mehta - The Journal of Organic Chemistry, 2023 - ACS Publications
We report late-stage ring-opening metathesis (ROM), ring-rearrangement metathesis (RRM),
and ring-closing metathesis (RCM) approaches to generate expanded pentacycloundecane …

Approaches to 1, 4‐Disubstituted Cubane Derivatives as Energetic Materials: Design, Theoretical Studies and Synthesis

S Lal, A Bhattacharjee, A Chowdhury… - Chemistry–An Asian …, 2022 - Wiley Online Library
Abstract Novel 1, 4‐disubstituted cubane derivatives have been designed and selected
ones have been successfully synthesized and characterized by various analytical and …

Silver(I)-Promoted ipso-Nitration of Carboxylic Acids by Nitronium Tetrafluoroborate

P Natarajan, R Chaudhary… - The Journal of Organic …, 2015 - ACS Publications
A novel and efficient method for the regioselective nitration of a series of aliphatic and
aromatic carboxylic acids to their corresponding nitro compounds using nitronium …

Thermal behavior and decomposition mechanism of three nitrate energetic materials: TNNP, TNOP and DNHM

B He, K Yang, E Xiutianfeng, M Wang, Z Meng… - Journal of Analytical and …, 2022 - Elsevier
Thermal decomposition of three new energetic materials, 5-nitratomethyl-1, 3, 5-
trinitrohexahydropyrimidine (TNNP), 5–methylnitrate‐1, 5–dinitrooxazine (TNOP) and 1, 3 …

Synthesis and energetic properties of high-nitrogen substituted bishomocubanes

S Lal, L Mallick, S Rajkumar, OP Oommen… - Journal of Materials …, 2015 - pubs.rsc.org
Synthesis, thermodynamic characterization, and energetic properties of three novel high-
nitrogen bishomocubane-based compounds DADMBHC, DTetzBHC and DPTrizDMBHC are …

Theoretical studies on the propulsive and explosive performance of strained polycyclic cage compounds

L Mallick, S Lal, S Reshmi, INN Namboothiri… - New Journal of …, 2017 - pubs.rsc.org
Compounds consisting of a carbon-based cage have a highly strained molecular structure
and have become the subject of interest in recent years because they possess high heat of …

Pentacycloundecane (PCUD)‐Based Cage Frameworks as Potential Energetic Materials: Syntheses and Characterization

S Kotha, SR Cheekatla, S Lal, L Mallick… - Asian Journal of …, 2020 - Wiley Online Library
A new variety of cage frameworks containing pentacycloundecane (PCUD) were
synthesized. These compounds contain azide and triazole units. Four new cage frameworks …

Synthesis and energetic properties of homocubane based high energy density materials

S Lal, A Chowdhury, N Kumbhakarna… - Organic Chemistry …, 2021 - pubs.rsc.org
The energetic properties of homocubane derivatives have been evaluated for the first time.
The newly synthesized compounds have been fully characterized by spectroscopic methods …