The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

In 1967 Pederson reported the synthesis of macrocyclic crown ethers and their ability to
selectively bind alkali and alkaline earth ions, 1, 2 and since then supramolecular …

The idea of synthesising polynuclear cage compounds without strictly designing the final
product is an extremely productive means of producing new polymetallic cages. Some of the …

Cyclophanes, especially those where pyridinium units in conjugation with each other are
linked up face-to-face within platforms that are held approximately 7 Å apart by rigid linkers …

Publisher Summary This chapter discusses high-nuclearity paramagnetic 3d-metal
complexes with oxygen-and nitrogen-donor ligands. The studies of high-nuclearity iron …

This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Library generation experiments are a key part of the discovery of new materials, methods,
and models in chemistry, but the question of how to generate high quality libraries to enable …

The impact that the anion and alkyl group has on the electronic structures and magnetic
properties of four mononuclear Mn (III) complexes is explored in [Mn (salEen-Br) 2] Y …

Complexes of high nuclearity, symmetry, and architectural beauty have long fascinated
chemists, owing both to their aesthetically pleasing nature and to their often interesting …

The synthesis and characterization of a high-nuclearity FeIII/O/arsinate cluster is reported
within the salt [Fe36O12 (OH) 6 (O2AsMe2) 63 (O2CH) 3 (H2O) 6](NO3) 12 (1). The …