The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Among the wide variety of organometallic compounds, the relatively cheap and safely
handled nontransition-metal derivatives, in particular organolithium, organomagnesium …

The addition of π‐allylmetal complexes to carbonyls is the most important route to
homoallylic alcohols. This study reports the first photocatalytic generation of π‐allyltitanium …

Transformations using organometallic complexes have played a central role in modern
organic synthesis. The types of reactions based on organometallic complexes can be …

Cp2TiCl2-Catalyzed Photoredox Allylation of Aldehydes with Visible Light | ACS Catalysis
ACS ACS Publications C&EN CAS Find my institution Log In ACS Catalysis ACS Publications …

Revised version: the first total synthesis of indoxamycin B leads to a stereochemical
reassignment of the natural product. The synthetic route features an efficient …

Cyclopropanols are valuable synthetic intermediates because of their facile, selective ring-
opening reactions to afford intermediates synthetically useful for subsequent structural …

The preparation of homoallylic alcohols by addition of organometallic allyl compounds to
carbonyls is an important strategy in organic chemistry. Allylating organometallic cobalt …

Nitrogen fixation using transition metals is a fascinating process. We have already reported
the incorporation of molecular nitrogen into organic compounds using a titanium–nitrogen …

Versatility of titanium: Titanocene (III) complexes catalyze Barbier‐type allylations,
intramolecular crotylations (cyclizations), and prenylations of a wide range of aldehydes and …