The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

We present a wide-ranging interrogation of the border between single-molecule and solid-
state magnetism through a study of erbium-based Ising-type magnetic compounds with a …

Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …

Complete active space self-consistent field (CASSCF) combined with restricted active space
spin interaction with spin–orbit coupling (RASSI-SO) was used to probe why single-ion …

Single-ion magnets (SIMs) and single-molecule magnets (SMMs) are typically made up of
3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal …

Abstract Solvation of [(CNT) Ln (η8‐COT)](Ln= La, Ce, Nd, Tb, Er; CNT= cyclononatetraenyl,
ie, C9H9−; COT= cyclooctatetraendiid, ie, C8H82−) complexes with tetrahydrofuran (THF) …

A new pair of multifunctional Zn (II)–Yb (III) complex enantiomers based on a chiral amine-
phenol ligand,[YbZn2 (SS/RR-L) 2 (H2O) 4](ClO4) 3· 5H2O (S-1 and R-1)[H2L=(SS/RR) …

Dipolar coupling is rarely invoked as a driving force for slow relaxation dynamics in
lanthanide-based single-molecule magnets, though it is often the strongest mechanism …