Electrocatalysis as an enabling technology for organic synthesis

LFT Novaes, J Liu, Y Shen, L Lu… - Chemical Society …, 2021 - pubs.rsc.org
Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …

Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

A review on photo-, electro-and photoelectro-catalytic strategies for selective oxidation of alcohols

D Tang, G Lu, Z Shen, Y Hu, L Yao, B Li, G Zhao… - Journal of Energy …, 2023 - Elsevier
Traditional conversion of alcohols into carbonyl compounds exists a few drawbacks such as
harsh reaction conditions, production of large amounts of hazardous wastes, and poor …

New redox strategies in organic synthesis by means of electrochemistry and photochemistry

J Liu, L Lu, D Wood, S Lin - ACS Central Science, 2020 - ACS Publications
As the breadth of radical chemistry grows, new means to promote and regulate single-
electron redox activities play increasingly important roles in driving modern synthetic …

Electrochemical oxidation of organic molecules at lower overpotential: Accessing broader functional group compatibility with electron− proton transfer mediators

F Wang, SS Stahl - Accounts of chemical research, 2020 - ACS Publications
Conspectus Electrochemical organic oxidation reactions are highly appealing because
protons are often effective terminal electron acceptors, thereby avoiding undesirable …

Cyclic voltammetry and chronoamperometry: mechanistic tools for organic electrosynthesis

M Rafiee, DJ Abrams, L Cardinale, Z Goss… - Chemical Society …, 2024 - pubs.rsc.org
Electrochemical methods offer unique advantages for chemical synthesis, as the reaction
selectivity may be controlled by tuning the applied potential or current. Similarly, measuring …

Redox: Organic robust radicals and their polymers for energy conversion/storage devices

K Hatakeyama-Sato, K Oyaizu - Chemical Reviews, 2023 - ACS Publications
Persistent radicals can hold their unpaired electrons even under conditions where they
accumulate, leading to the unique characteristics of radical ensembles with open-shell …

Recent progress in the applications of boron doped diamond electrodes in electroanalysis of organic compounds and biomolecules–A review

S Baluchová, A Daňhel, H Dejmková, V Ostatná… - Analytica chimica …, 2019 - Elsevier
This review summarizes progress in electroanalysis of organic compounds and
biomacromolecules by means of bare BDD-based electrodes for the period of 2009–2018 …

Electro‐synthesis of organic compounds with heterogeneous catalysis

T Ali, H Wang, W Iqbal, T Bashir, R Shah… - Advanced …, 2023 - Wiley Online Library
Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science,
medicinal chemistry, and future industrial applications in energy storage and conversion. To …

Electrochemical aminoxyl-mediated oxidation of primary alcohols in lignin to carboxylic acids: polymer modification and depolymerization

M Rafiee, M Alherech, SD Karlen… - Journal of the American …, 2019 - ACS Publications
An electrochemical process has been developed for chemoselective oxidation of primary
alcohols in lignin to the corresponding carboxylic acids. The electrochemical oxidation …